Charge reversal fourier transform ion cyclotron resonance mass spectrometry

被引：0
|
作者：
机构：
[1] Lobodin, Vladislav V.
[2] Savory, Joshua J.
[3] Kaiser, Nathan K.
[4] Dunk, Paul W.
[5] 1,Marshall, Alan G.
来源：
Marshall, A.G. (marshall@magnet.fsu.edu) | 1600年 / Springer Science and Business Media, LLC卷 / 24期
关键词：
We report the first charge reversal experiments performed by tandem-in-time rather than tandem-in-space MS/MS. Precursor odd-electron anions from fullerene C60, and even-electron ions from 2,7-di-tert-butylfluorene-9- carboxylic acid and 3,3′-bicarbazole were converted into positive product ions (-CR+) inside the magnet of a Fourier transform ion cyclotron resonance mass spectrometer. Charge reversal was activated by irradiating precursor ions with high energy electrons or UV photons: the first reported use of those activation methods for charge reversal. We suggest that high energy electrons achieve charge reversal in one step as double electron transfer, whereas UV-activated -CR+ takes place stepwise through two single electron transfers and formally corresponds to a neutralization-reionization (-NR+) experiment.[Figure not available: see fulltext.] © 2012 American Society for Mass Spectrometry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
相关论文
共 50 条
  • [1] Charge Reversal Fourier Transform Ion Cyclotron Resonance Mass Spectrometry
    Lobodin, Vladislav V.
    Savory, Joshua J.
    Kaiser, Nathan K.
    Dunk, Paul W.
    Marshall, Alan G.
    JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2013, 24 (02) : 213 - 221
  • [2] Fourier transform ion cyclotron resonance mass spectrometry
    Marshall, AG
    FOURIER TRANSFORM SPECTROSCOPY, 1998, (430): : 3 - 13
  • [3] Fourier Transform Ion Cyclotron Resonance Mass Spectrometry at the Cyclotron Frequency
    Nagornov, Konstantin O.
    Kozhinov, Anton N.
    Tsybin, Yury O.
    JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2017, 28 (04) : 768 - 780
  • [4] Fourier transform ion cyclotron resonance mass spectrometry: A primer
    Marshall, AG
    Hendrickson, CL
    Jackson, GS
    MASS SPECTROMETRY REVIEWS, 1998, 17 (01) : 1 - 35
  • [5] Fourier transform ion cyclotron resonance mass spectrometry - Preface
    Marshall, AG
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1996, 157 : R9 - R11
  • [6] Focus on Fourier transform ion cyclotron resonance mass spectrometry
    Gross, ML
    JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2001, 12 (03) : 243 - 244
  • [7] Fourier transform ion cyclotron resonance mass spectrometry at the true cyclotron frequency
    Nagornov, Konstantin O.
    Tsybin, Oleg Y.
    Nicol, Edith
    Kozhinov, Anton N.
    Tsybin, Yury O.
    MASS SPECTROMETRY REVIEWS, 2022, 41 (02) : 314 - 337
  • [8] SIMION modeling of ion image charge detection in Fourier transform ion cyclotron resonance mass spectrometry
    Hendrickson, Christopher L.
    Beu, Steven C.
    Blakney, Greg T.
    Marshall, Alan G.
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2009, 283 (1-3) : 100 - 104
  • [9] Quantitation of ion abundances in Fourier transform ion cyclotron resonance mass spectrometry
    Goodner, KL
    Milgram, KE
    Williams, KR
    Watson, CH
    Eyler, JR
    JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 1998, 9 (11) : 1204 - 1212
  • [10] Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Applications for Metabolomics
    Cochran, Darcy
    Powers, Robert
    BIOMEDICINES, 2024, 12 (08)
12345