Preparation of emulsifier-free polystyrene by conventional emulsion polymerization with a hydrolysable emulsifier

被引：0
|
作者：
Itoh, Y. [1 ]
Akasaka, R. [1 ]
Takahashi, K. [1 ]
机构：
[1] Department of Functional Polymer Science, Faculty of Textile Science and Technology, Shinshu University, Nagano 386-8567, Japan
来源：
Journal of Applied Polymer Science | 2008年 / 108卷 / 01期
关键词：
An alkali-hydrolyzable surfactant; (1-tetradecyloxycarbonyl) trimethylammonium chloride; was used as an emulsifier for emulsion polymerization of styrene in water. The polymerization yielded a high molecular-weight polymer almost quantitatively. Addition of a small amount of NaOH to the resulting latex solution precipitated the polymer immediately. Analysis of the centrifuged solid indicated almost perfection of both recovery of the polymer and removal of surface-active species from it. Minimization of ionic species in the polymer solid was confirmed by a high contact angle of the polymer film with water. © 2007 Wiley Periodicals; Inc;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：358 / 361
相关论文
共 50 条
  • [21] A new kinetic model of emulsifier-free emulsion polymerization
    Yan, C
    Cheng, SY
    Feng, LX
    MACROMOLECULAR SYMPOSIA, 2000, 150 : 127 - 134
  • [22] Kinetics of emulsifier-free emulsion polymerization of methyl methacrylate
    Tanrisever, T
    Okay, O
    Sonmezoglu, IC
    JOURNAL OF APPLIED POLYMER SCIENCE, 1996, 61 (03) : 485 - 493
  • [23] PRACTICAL ASPECTS OF THE EMULSIFIER-FREE EMULSION POLYMERIZATION OF STYRENE
    SHOULDICE, GTD
    VANDEZANDE, GA
    RUDIN, A
    EUROPEAN POLYMER JOURNAL, 1994, 30 (02) : 179 - 183
  • [24] Preparation of high molecular weight polyvinyl alcohol by emulsifier-free emulsion polymerization
    Hong, Xinqiu
    Zou, Liming
    Zhang, Jingyang
    Wang, Liujian
    2020 2ND INTERNATIONAL CONFERENCE ON GEOSCIENCE AND ENVIRONMENTAL CHEMISTRY (ICGEC 2020), 2020, 206
  • [25] Synthesis of polystyrene-silica nanoparticles via RAFT emulsifier-free emulsion polymerization
    Tumnantong, Dusadee
    Rempel, Garry L.
    Prasassarakich, Pattarapan
    EUROPEAN POLYMER JOURNAL, 2016, 80 : 145 - 157
  • [26] Emulsifier-free emulsion polymerization of N-butyl methacrylate
    Bataille, P
    Almassi, M
    Inoue, M
    JOURNAL OF APPLIED POLYMER SCIENCE, 1998, 67 (10) : 1711 - 1719
  • [27] Effect of electrolyte on the emulsifier-free emulsion polymerization of vinyl acetate
    Moustafa, AB
    AbdelHakim, AA
    Sayyah, SM
    Mohamed, GA
    JOURNAL OF APPLIED POLYMER SCIENCE, 1997, 66 (04) : 711 - 715
  • [28] Formation of monodispersed polymer particles in emulsifier-free emulsion polymerization
    Zhang, MG
    Weng, ZX
    Huang, ZM
    Pan, ZR
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1998, 19 (09): : 1518 - 1521
  • [29] Preparation of Nanocapsules via Emulsifier-Free Miniemulsion Polymerization
    Barari, Mohammad
    Faridi-Majidi, Reza
    Madani, Mohammad
    Sharifi-Sanjani, Naser
    Oghabian, Mohammad Ali
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2009, 9 (07) : 4348 - 4352
  • [30] Enzymatic emulsifier-free emulsion polymerization to prepare polystyrene particles using horseradish peroxidase as a catalyst
    Kohri, Michinari
    Uzawa, Satoshi
    Kobayashi, Ayaka
    Fukushima, Haruka
    Taniguchi, Tatsuo
    Nakahira, Takayuki
    POLYMER JOURNAL, 2013, 45 (03) : 354 - 358
12345