Glass forming ability and magnetic properties of Fe-Nd-B-Zr bulk metallic glasses

被引:0
|
作者
Liu, Fan-Mao [1 ]
Zhang, Hui-Yan [1 ]
Zhang, Tao [1 ]
机构
[1] School of Materials Science and Engineering, Beihang University, Beijing
来源
Cailiao Gongcheng/Journal of Materials Engineering | 2014年 / 10期
关键词
Fe-based bulk metallic glass; Glass forming ability; Hard magnetic property; Nanocomposite permanent magnet;
D O I
10.11868/j.issn.1001-4381.2014.10.002
中图分类号
学科分类号
摘要
Permanent magnets with Fe-Nd-B bulk metallic glasses as precursors was fabricated. Trace zirconium was added into Fe70Nd10B20 ternary alloy and its adjacent composition. The samples were prepared by spin quenching and copper mold casting, and the glass forming ability was characterized by XRD and DSC. Then the Fe70Nd9B20Zr1 bulk metallic glasses were crystallized by annealing treatment. The crystallization phases were analyzed by XRD and the magnetic properties in various crystallization stages were characterized by VSM. The results show that the glass forming ability of the alloys is enhanced, and Fe-Nd-B-Zr bulk metallic glasses with critical diameter of 2 mm are obtained in alloys containing 1% atom fraction Zr. The optimum hard magnetic properties of Fe70Nd9B20Zr1 bulk metallic glasses can be achieved after annealing at 946K for 600s. The remanence (Br), coercive field (iHc) and maximum energy product (BH)max are 0.54 T, 348 kA/m and 24.1 kJ/m3, respectively. This alloy system can be applied to directly synthesize nanocomposite permanent magnets by the process of casting and subsequent crystallization.
引用
收藏
页码:6 / 10
页数:4
相关论文
共 24 条
  • [1] Coehoorn R., de Mooij D.B., Duchateau J.P.W.B., Et al., Novel permanent magnetic materials made by rapid quenching , Journal de Physique (France), C8, 49, pp. 669-670, (1988)
  • [2] Kneller E.F., Hawig R., The exchange-spring magnet: A new materials principle for permanent magnets, IEEE Transactions on Magnetics, 27, 4, pp. 3558-3600, (1991)
  • [3] Manaf A., Buckley R.A., Davies H.A., New nanocrystalline high-remanence Nd-Fe-B by rapid solidification , Journal of Magnetism and Magnetic Materials, 128, 3, pp. 302-306, (1993)
  • [4] Inoue A., Takeuchi A., Makino A., Et al., Hard magnetic properties of Fe-Nd-B alloys containing intergranular amorphous phase , IEEE Transactions on Magnetics, 31, 6, pp. 3626-3628, (1995)
  • [5] Schrelf T., Fischer R., Fidler J., Et al., Two-and three-dimensional calculation of remanence enhancement of rare-earth based composite magnets , Journal of Applied Physics, 76, 10, pp. 7053-7058, (1994)
  • [6] Skomski R., Coey J.M.D., Giant energy product in nanostructured two-phase magnets , Physical Review B, 48, 21, pp. 15812-15816, (1993)
  • [7] Zhang W., Inoue A., Bulk nanocomposite permanent magnets produced by crystallization of (Fe, Co)-(Nd, Dy)-B bulk glassy alloy , Applied Physics Letters, 80, 9, pp. 1610-1612, (2002)
  • [8] Pawlik P., Davies H.A., Glass formability of Fe-Co-Pr-Dy-Zr-B alloys and magnetic properties following devitrification , Scirpta Materialia, 49, 8, pp. 755-760, (2003)
  • [9] Zhang W., Inoue A., Bulk nanocomposite permanent magnets produced by crystallization of Fe<sub>66.5</sub>Co<sub>10</sub>Pr<sub>3.5</sub>B<sub>20</sub> bulk glassy alloy , Journal of Applied Physics, 91, 10, pp. 8834-8836, (2002)
  • [10] Zhao W.J., The study on magnetic properties and crystallized behavior for the Fe-(Nd, Co, Zr)-Y-B bulk amorphous alloy , pp. 1-55, (2007)