Characterization of self-assembled monolayers of fullerene derivatives on gold surfaces: Implications for device evaluations

被引：0
|
作者：
Shirai, Yasuhiro [1 ]
Cheng, Long [1 ]
Chen, Bo [1 ]
Tour, James M. [1 ]
机构：
[1] Department of Chemistry, Smalley Institute for Nanoscale Science and Technology, Rice University, 6100 Main Street, Houston, TX 77005, United States
来源：
Journal of the American Chemical Society | 2006年 / 128卷 / 41期
关键词：
The widely employed approach to self-assembly of fullerene derivatives on gold can be complicated due to multilayer formations and head-to-tail assemblies resulting from the strong fullerene fullerene and fullerene-gold interactions. These anomalies were not examined in detail in previous studies on fullerene self-assembled monolayers (SAMs) but were clearly detected in the present work using surface characterization techniques including ellipsometry; cyclic voltammetry (CV); and X-ray photoelectron spectroscopy (XPS). This is the first time that SAMs prepared from fullerene derivatives of thiols/thiol esters/disulfides have been analyzed in detail; and the complications due to multilayer formations and head-to-tail assemblies were revealed. Specifically; we designed and synthesized several fullerene derivatives based on thiols; thiol acetates; and disulfides to address the characterization requirements; and these are described and delineated. These studies specifically address the need to property characterize and control fullerene-thiol assemblies on gold before evaluating subsequent device performances. © 2006 American Chemical Society;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：13479 / 13489
相关论文
共 50 条
  • [1] Characterization of self-assembled monolayers of fullerene derivatives on gold surfaces: Implications for device evaluations
    Shirai, Yasuhiro
    Cheng, Long
    Chen, Bo
    Tour, James M.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (41) : 13479 - 13489
  • [2] A fullerene helical peptide: synthesis, characterization and formation of self-assembled monolayers on gold surfaces
    Nasrallah, Houssein
    Rabah, Jad
    Van Bui-Thi-Tuyet
    Baczko, Krystyna
    Fensterbank, Helene
    Bourdreux, Flavien
    Goncalves, Anne-Marie
    Declerck, Valerie
    Boujday, Souhir
    Humblot, Vincent
    Wright, Karen
    Vallee, Anne
    Allard, Emmanuel
    NEW JOURNAL OF CHEMISTRY, 2018, 42 (24) : 19423 - 19432
  • [3] Self-assembled fullerene derivatives layers on gold and silicon surfaces
    Lee, H
    Jeon, IC
    SYNTHETIC METALS, 1997, 86 (1-3) : 2297 - 2298
  • [4] Electrochemical characterization of self-assembled monolayers at gold surfaces.
    Lehnes, JM
    Goldsby, KA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 220 : U464 - U465
  • [5] Self-assembled monolayers of chromophores on gold surfaces
    Kriegisch, V
    Lambert, C
    SUPERMOLECULAR DYE CHEMISTRY, 2005, 258 : 257 - 313
  • [6] Carboranethiol self-assembled monolayers on gold surfaces
    Sohrabnia, Nima
    Yavuz, Adem
    Yilmaz, Aysen
    Danisman, Mehmet Fatih
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [7] STRUCTURE AND BINDING OF ALKANETHIOLATES ON GOLD AND SILVER SURFACES - IMPLICATIONS FOR SELF-ASSEMBLED MONOLAYERS
    SELLERS, H
    ULMAN, A
    SHNIDMAN, Y
    EILERS, JE
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (21) : 9389 - 9401
  • [8] Cationic systems as self-assembled monolayers on gold surfaces
    Ng, YF
    Strutwolf, J
    Garratt, PJ
    Williams, DE
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 464 (02) : 263 - 267
  • [9] Mixed carboranethiol self-assembled monolayers on gold surfaces
    Yavuz, Adem
    Sohrabnia, Nima
    Yilmaz, Aysen
    Danisman, M. Fatih
    APPLIED SURFACE SCIENCE, 2017, 413 : 233 - 241
  • [10] Self-assembled fullerene derivatives on quartz glass surfaces
    Shabanova, E
    Komolov, A
    Schaumburg, K
    PHYSICS OF LOW-DIMENSIONAL STRUCTURES, 2000, 3-4 : 37 - 44
12345