Recent advances in application of metal-organic frameworks (MOFs) as adsorbent and catalyst in removal of persistent organic pollutants (POPs)

被引：136
作者：
Naghdi S. [1 ]
Shahrestani M.M. [2 ,3 ]
Zendehbad M. [4 ]
Djahaniani H. [2 ,3 ]
Kazemian H. [2 ,3 ]
Eder D. [1 ]
机构：
[1] Institute of Material Chemistry, Technische Universität Wien, Vienna
[2] Northern Analytical Lab Services (Northern BC's Environmental and Climate Solutions Innovation Hub), University of Northern British Columbia, Prince George, BC
[3] Chemistry Department, Faculty of Science and Engineering, University of Northern British Columbia, Prince George, BC
[4] Institute of Soil Physics and Rural Water Management, Department of Water, Atmosphere and Environment, University of Natural Resources and Life Sciences, Vienna
来源：
Journal of Hazardous Materials | 2023年 / 442卷
基金：
奥地利科学基金会; 加拿大自然科学与工程研究理事会;
关键词：
Adsorptive removal of environmental contaminants; Metal-organic frameworks (MOFs); Persistent organic pollutants (POPs); Photocatalytic degradation;
D O I：
10.1016/j.jhazmat.2022.130127
中图分类号：
学科分类号：
摘要：
The presence of persistent organic pollutants (POPs) in the aquatic environment is causing widespread concern due to their bioaccumulation, toxicity, and possible environmental risk. These contaminants are produced daily in large quantities and released into water bodies. Traditional wastewater treatment plants are ineffective at degrading these pollutants. As a result, the development of long-term and effective POP removal techniques is critical. In water, adsorption removal and photocatalytic degradation of POPs have been identified as energy and cost-efficient solutions. Both technologies have received a lot of attention for their efforts to treat the world's wastewater. Photocatalytic removal of POPs is a promising, effective, and long-lasting method, while adsorption removal of persistent POPs represents a simple, practical method, particularly in decentralized systems and isolated areas. It is critical to develop new adsorbents/photocatalysts with the desired structure, tunable chemistry, and maximum adsorption sites for highly efficient removal of POPs. As a class of recently created multifunctional porous materials, Metal-organic frameworks (MOFs) offer tremendous prospects in adsorptive removal and photocatalytic degradation of POPs for water remediation. This review defines POPs and discusses current research on adsorptive and photocatalytic POP removal using emerging MOFs for each type of POPs. © 2022 The Authors
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