Paramagnetic centers in nanocrystalline TiC/C system

被引：0
|
作者：
Guskos, N. [1 ,2 ]
Bodziony, T. [2 ]
Maryniak, M. [2 ]
Typek, J. [2 ]
Biedunkiewicz, A. [3 ]
机构：
[1] Solid State Physics, Department of Physics, University of Athens, Panepistimiopolis, 15 784 Zografos, Athens, Greece
[2] Institute of Physics, Szczecin University of Technology, Al. Piastow 17, 70-310 Szczecin, Poland
[3] Institute of Material Engineering, Szczecin University of Technology, Al. Piastow 19, 70-310 Szczecin, Poland
来源：
Journal of Alloys and Compounds | 2008年 / 455卷 / 1-2期
关键词：
Electron paramagnetic resonance is applied to study the defect centers in nanocrystalline titanium carbide dispersed in carbon matrix (TiCx/C) synthesized by the non-hydrolytic sol-gel process. The presence of Ti3+ paramagnetic centers is identified below 120 K along with a minor contribution from localized defect spins coupled with the conduction electron system in the carbon matrix. The temperature dependence of the resonance intensity of the latter signal indicates weak antiferromagnetic interactions. The presence of paramagnetic centers connected with trivalent titanium is suggested to be the result of chemical disorder; which can be further related to the observed anomalous behavior of conductivity; hardness; and corrosion resistance of nanocrystalline TiCx/C. © 2007 Elsevier B.V. All rights reserved;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：52 / 54
相关论文
共 50 条
  • [31] Effects of boron addition on the microstructure and properties of in situ synthesis TiC reinforced Cu-Ti-C composites
    Ding, Haimin
    Liu, Qing
    Wang, Xianlong
    Fan, Xiaoliang
    Krzystyniak, Matthew
    Glandut, Nicolas
    Li, Chong
    JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 766 : 66 - 73
  • [32] Growth Structure and Properties of Gradient Nanocrystalline Coatings of the Ti–Al–Si–Cu–N System
    S. V. Ovchinnikov
    Yu. P. Pinzhin
    Russian Physics Journal, 2016, 59 : 799 - 808
  • [33] Mechanical Behavior of TiN/TiC-n Multilayer Coatings and Ti(C,N) Multicomponent Coatings Produced by PACVD
    M. Azadi
    A. S. Rouhaghdam
    S. Ahangarani
    Strength of Materials, 2016, 48 : 279 - 289
  • [34] Spark plasma sintering of Nb/Ti3Al(Si)C2-TiC laminated composites
    Kashkarov, E. B.
    Krotkevich, D. G.
    Abdulmenova, A. V.
    Ivashutenko, A. S.
    Perevislov, S. N.
    Lider, A. M.
    Travitzky, N.
    MATERIALIA, 2023, 27
  • [35] MECHANICAL BEHAVIOR OF TiN/TiC-n MULTILAYER COATINGS AND Ti(C,N) MULTICOMPONENT COATINGS PRODUCED BY PACVD
    Azadi, M.
    Rouhaghdam, A. S.
    Ahangarani, S.
    STRENGTH OF MATERIALS, 2016, 48 (02) : 279 - 289
  • [36] Microstructure and mechanical properties of Al/TiC and Al/(Ti,W)C nanocomposites fabricated via in situ casting method
    Maziarz, W.
    Wojcik, A.
    Chulist, R.
    Bigos, A.
    Kurtyka, P.
    Szymanski, L.
    Zabaleta, A. Jimenez
    de Cortazar, M. Garcia
    Olejnik, E.
    JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2024, 28 : 1852 - 1863
  • [37] Optimization of powder metallurgy parameters of TiC- and B4C-reinforced aluminium composites by Taguchi method
    Vairamuthu, J.
    Kumar, A. Senthil
    Stalin, B.
    Ravichandran, M.
    TRANSACTIONS OF THE CANADIAN SOCIETY FOR MECHANICAL ENGINEERING, 2021, 45 (02) : 249 - 261
  • [38] Synthesis and performance of TiB2-B4C composites by high pressure of TiC-B mixture
    Hu, Meihua
    Bi, Ning
    Liu, Mingming
    Li, Shangsheng
    Su, Taichao
    INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2020, 17 (04) : 1629 - 1635
  • [39] Study of the Phase Composition and Microstructure of Complex Carbide (Ti, W)C Obtained by Spark Plasma Sintering of WC and TiC Powders
    Terent'ev, A. V.
    Blagoveshchenskij, Yu. V.
    Isaeva, N. V.
    Lancev, E. A.
    Smetanina, K. E.
    Murashov, A. A.
    Nokhrin, A. V.
    Boldin, M. S.
    Chuvil'deev, V. N.
    Shcherbak, G. V.
    INORGANIC MATERIALS-APPLIED RESEARCH, 2024, 15 (03) : 696 - 706
  • [40] Structure and mechanical properties of nc-TiC/a-C:H nanocomposite films deposited by filtered cathodic arc technique
    Yu-Hao Zhai
    Yu-Juan Zhang
    Yi Peng
    Sheng-Mao Zhang
    Ping-Yu Zhang
    Xiao-Min Zhang
    Rare Metals, 2016, 35 : 177 - 183
12345