Ammonia-borane: The hydrogen source par excellence?

被引：877
作者：
Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM, United States [1 ]
机构：
[1] Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM
来源：
Dalton Trans. | 2007年 / 25卷 / 2613-2626期
关键词：
D O I：
10.1039/b703053c
中图分类号：
学科分类号：
摘要：
Ammonia-borane, H3NBH3, is an intriguing molecule for chemical hydrogen storage applications. With both protic N-H and hydridic B-H bonds, three H atoms per main group element, and a low molecular weight, H 3NBH3 has the potential to meet the stringent gravimetric and volumetric hydrogen storage capacity targets needed for transportation applications. Furthermore, devising an energy-efficient chemical process to regenerate H3NBH3 from dehydrogenated BNHx material is an important step towards realization of a sustainable transportation fuel. In this perspective we discuss current progress in catalysis research to control the rate and extent of hydrogen release and preliminary efforts at regeneration of H3NBH3. © The Royal Society of Chemistry.
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页码：2613 / 2626
页数：13
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