Chelation properties of poly(2-hydroxy-4-acryloyloxybenzophenone) resins toward some divalent metal ions

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作者
Zalloum, Ruba M. [1 ]
Mubarak, Mohammad S. [1 ]
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[1] Department of Chemistry, Faculty of Science, University of Jordan, Amman 11942, Jordan
来源
Journal of Applied Polymer Science | 2008年 / 109卷 / 05期
关键词
The chelation behavior of poly(2-hydroxy-4-acryloyloxybenzophenone) [poly(2H4ABP) or polymer I] obtained through the free-radical polymerization of 2-hydroxy-4-acryloyloxybenzophenone monomer and for crosslinked polymers prepared from the monomer and known amounts of the crosslinker divinylbenzene (DVB) [4 mol % of DVB for polymer II; 8 mol % of DVB for polymer III; and 16 mol 16% of DVB for polymer IV] toward the divalent metal ions Cu2+; Ni2+; Zn2+; and Pb2+ in aqueous solution was studied by a batch equilibration technique as a function of contact time and pH. The effect of the crosslinker; DVB; was also studied. The metal-ion uptake of the polymers was determined with atomic absorption spectroscopy; and the highest uptake was achieved at pH 7.0 for polymers I; II; III; and IV. The selectivity and binding capacity of the resins toward the investigated divalent metal ions are discussed. © 2008 Wiley Periodicals; Inc;
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页码:3180 / 3184
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