Combined treatment of air stripping-O3 and H2O2 oxidation for high concentration nitrobenzene-containing wastewater enhanced by high gravity technology

被引:0
|
作者
Feng, Zhi-Rong [1 ,2 ]
Jiao, Wei-Zhou [1 ,2 ]
Liu, You-Zhi [1 ,2 ]
Guo, Liang [1 ,2 ]
Xu, Cheng-Cheng [1 ,2 ]
Yu, Li-Sheng [1 ,2 ]
Wang, Yong-Hong [1 ,2 ]
机构
[1] Research Center of Shanxi Province for High Gravity Chemical Engineering and Technology, North University of China, Taiyuan
[2] Shanxi Province Key Laboratory of Higee-Oriented Chemical Engineering, Taiyuan
来源
Hanneng Cailiao/Chinese Journal of Energetic Materials | 2015年 / 23卷 / 06期
关键词
Air stripping; High gravity; Nitrobenzene; Ozone; Peroxide of hydrogen; Process intensification;
D O I
10.11943/j.issn.1006-9941.2015.06.016
中图分类号
学科分类号
摘要
To reduce the content of nitrobenzene in wastewater, an air stripping-O3/H2O2 oxidation treatment process enhanced by high gravity technology was established for the first time. The pretreatment of high concentration nitrobenzene-containing wastewater was conducted by air stripping method, which was enhanced by high gravity technology. The effects of high gravity factor β, gas-flow rate G, liquid-flow rate L and stripping times on the nitrobenzene stripping efficiency were investigated. The experimental results show that the combination of high gravity technology can effectively improve the nitrobenzene removal rate. When the G=20 m3·h-1, L=20 L·h-1, β=80, the concentration of nitrobenzene after stripping for 10 times is decreased to 100 mg·L-1. Then the changes of stripping efficiency are significantly weakened. The lower content wastewater is further treated by advanced oxidation process of O3/H2O2 enhanced by high gravity technology. When L=120 L·h-1, β=80, gas phase O3 concentration CO3=50 mg·L-1, the concentration of H2O2 CH2O2=4. 9 mmol·L-1, initial pH=10.5 and the processing time is 25 min, the removal efficiency of nitrobenzene can reach 99.6% and BOD5/CODCr=0.38; the wastewater treated can meet the standard of biochemistry treatment of integrated wastewater discharge standard(GB8978-1996). ©, 2015, Institute of Chemical Materials, China Academy of Engineering Physics. All right reserved.
引用
收藏
页码:589 / 593
页数:4
相关论文
共 22 条
  • [1] Chang S.-J., Liu Y.-C., Treatment of TNT wastewater by supercritical water oxidation, Chinese Journal of Energetic Materials(Hanneng Cailiao), 15, 3, pp. 285-288, (2007)
  • [2] Jiao W.Z., Liu Y.Z., Liu W.L., Et al., Degradation of nitrobenzene-containing wastewater with O<sub>3</sub> and H<sub>2</sub>O<sub>2</sub> by high gravity technology, China Petroleum Processing & Petrochemical Technology, 15, 1, pp. 85-94, (2013)
  • [3] Wang H.-E., Sun J.-L., Yan S.-L., Et al., Waste-water treatment of diazodinitrophenel by white rot fungus-peat, Chinese Journal of Energetic Materials(Hanneng Cailiao), 21, 3, pp. 367-371, (2013)
  • [4] Oh B.T., Seo Y.S., Sudhakar D., Et al., Oxidative degradation of endotoxin by advanced oxidation process (O<sub>3</sub>/H<sub>2</sub>O<sub>2</sub> & UV/H<sub>2</sub>O<sub>2</sub>), Journal of Hazardous Materials, 279, pp. 105-110, (2014)
  • [5] Diao J.-X., Liu Y.-Z., Wang H., Et al., O<sub>3</sub>/H<sub>2</sub>O<sub>2</sub> oxidative treatment of TNT red-water in a rotating paced bed, Chinese Journal of Energetic Materials (Hanneng Cailiao), 15, 3, pp. 281-284, (2007)
  • [6] Wu Y.-G., Jiao J., Zhao D.-W., Et al., Advance oxidation process for treatment of waste water contaminated by explosives, Chinese Journal of Energetic Materials(Hanneng Cailiao), 11, 3, pp. 166-169, (2003)
  • [7] De Torres-Socias E., Fernandez-Calderero I., Oller I., Et al., Cork boiling wastewater treatment at pilot plant scale: Comparison of solar photo-Fenton and ozone (O<sub>3</sub>, O<sub>3</sub>/H<sub>2</sub>O<sub>2</sub>). Toxicity and biodegradability assessment, Chemical Engineering Journal, 234, pp. 232-239, (2013)
  • [8] Xue C.-F., Liu Y.-Z., Jiao W.-Z., Experimental study on treatment of acrylonitrile waste water by high gravity air stripping technology, Chemical Industry and Engineering Progress, 9, pp. 2501-2505, (2014)
  • [9] Quan X.J., Cheng Z.L., Xu F., Et al., Structural optimization of the porous section in a water-sparged aerocyclone reactor to enhance the air-stripping efficiency of ammonia, Journal of Environmental Chemical Engineering, 2, 2, pp. 1199-1206, (2014)
  • [10] Ghoreyshi A.A., Sadeghifar H., Entezarion F., Efficiency assessment of air stripping packed towers for removal of VOCs (volatile organic compounds) from industrial and drinking waters, Energy, 73, pp. 838-843, (2014)