Nitrogen doped anatase TiO2 sheets with dominant {001} facets for enhancing visible-light photocatalytic activity

The photocatalytic activity of TiO2 can be mainly improved from three approaches: (1) enhancing surface energy; (2) increasing availability of visible light and (3) improving the separation efficiency of photo-induced electrons and holes. Here, we report a one-step route to obtain nitrogen (N) doped TiO2 sheets with dominant {001} facets by a hydrothermal process. The XRD patterns confirm the better crystallinity. XPS spectrums show nitrogen acting as interstitial N or an O-Ti-N structure in TiO2 sheets. Compared with that of TiO2 sheets, the N doped TiO 2 sheets not only absorb visible light, but also have a large percentage of high reactive {001} facets, so the photocatalytic activities are greatly enhanced, as confirmed by the decomposition of methylene orange. © 2014 Elsevier Ltd.