Simple Fluctuations in Simple Glass Formers

被引:0
作者
Laudicina, Corentin C. L. [1 ]
Charbonneau, Patrick [2 ,3 ]
Hu, Yi [2 ]
Janssen, Liesbeth M. C. [1 ]
Morse, Peter K. [4 ,5 ]
Pihlajamaa, Ilian [1 ]
Szamel, Grzegorz [6 ]
机构
[1] Eindhoven Univ Technol, Dept Appl Phys, Soft Matter & Biol Phys, NL-5600 MB Eindhoven, Netherlands
[2] Duke Univ, Dept Chem, Durham, NC 27708 USA
[3] Duke Univ, Dept Phys, Durham, NC 27708 USA
[4] Princeton Univ, Dept Chem, Dept Phys, Princeton, NJ 08544 USA
[5] Princeton Univ, Princeton Inst Mat, Princeton, NJ 08544 USA
[6] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA
基金
荷兰研究理事会;
关键词
STOKES-EINSTEIN RELATION; MODE-COUPLING THEORY; SUPERCOOLED LIQUIDS; HETEROGENEITY; MOTION; SUSCEPTIBILITY; DIMENSIONALITY; TRANSITION; BREAKDOWN; DYNAMICS;
D O I
10.1021/acs.jpcb.4c05447
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Critical single-particle fluctuations associated with particle displacements are inherent to simple glass-forming liquids in the limit of large dimensions and leave a pseudocritical trace across all finite dimensions. This characteristic could serve as a crucial test for distinguishing between theories of glass formation. We here examine these critical fluctuations, as captured by the well-established non-Gaussian parameter, within both mode-coupling theory (MCT) and dynamical mean-field theory (DMFT) across dimensions for hard sphere fluids and for the minimally structured Mari-Kurchan model. We establish general scaling laws relevant to any liquid dynamics theory in large dimensions and show that the dimensional scalings predicted by MCT are inconsistent with those from DMFT. Simulation results for hard sphere fluids in moderately high dimensions align with the DMFT scenario, reinforcing the relevance of mean-field theory for capturing glass physics in finite dimensions. We identify potential adjustments to MCT to account for certain mean-field physics. Our findings also highlight that local structure and spatial dimensionality can affect single-particle critical fluctuations in nontrivial ways.
引用
收藏
页码:12237 / 12249
页数:13
相关论文
共 68 条
[1]   Spatial Dimensionality Dependence of Heterogeneity, Breakdown of the Stokes-Einstein Relation, and Fragility of a Model Glass-Forming Liquid [J].
Adhikari, Monoj ;
Karmakar, Smarajit ;
Sastry, Srikanth .
JOURNAL OF PHYSICAL CHEMISTRY B, 2021, 125 (36) :10232-10239
[2]   Fifth-order susceptibility unveils growth of thermodynamic amorphous order in glass-formers [J].
Albert, S. ;
Bauer, Th. ;
Michl, M. ;
Biroli, G. ;
Bouchaud, J. -P. ;
Loidl, A. ;
Lunkenheimer, P. ;
Tourbot, R. ;
Wiertel-Gasquet, C. ;
Ladieu, F. .
SCIENCE, 2016, 352 (6291) :1308-1311
[3]  
[Anonymous], 2012, Structural Glasses and Supercooled Liquids: Theory, Experiment, and Applications
[4]   DYNAMICS OF SUPERCOOLED LIQUIDS AND THE GLASS-TRANSITION [J].
BENGTZELIUS, U ;
GOTZE, W ;
SJOLANDER, A .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1984, 17 (33) :5915-5934
[5]   Spontaneous and induced dynamic correlations in glass formers. II. Model calculations and comparison to numerical simulations [J].
Berthier, L. ;
Biroli, G. ;
Bouchaud, J.-P. ;
Kob, W. ;
Miyazaki, K. ;
Reichman, D. R. .
JOURNAL OF CHEMICAL PHYSICS, 2007, 126 (18)
[6]   Finite Dimensional Vestige of Spinodal Criticality above the Dynamical Glass Transition [J].
Berthier, Ludovic ;
Charbonneau, Patrick ;
Kundu, Joyjit .
PHYSICAL REVIEW LETTERS, 2020, 125 (10)
[7]   Configurational entropy measurements in extremely supercooled liquids that break the glass ceiling [J].
Berthier, Ludovic ;
Charbonneau, Patrick ;
Coslovich, Daniele ;
Ninarello, Andrea ;
Ozawa, Misaki ;
Yaida, Sho .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2017, 114 (43) :11356-11361
[8]   Theoretical perspective on the glass transition and amorphous materials [J].
Berthier, Ludovic ;
Biroli, Giulio .
REVIEWS OF MODERN PHYSICS, 2011, 83 (02) :587-645
[9]   The RFOT Theory of Glasses: Recent Progress and Open Issues [J].
Biroli, Giulio ;
Bouchaud, Jean-Philippe .
COMPTES RENDUS PHYSIQUE, 2023, 24 :1-16
[10]   Critical fluctuations and breakdown of the Stokes-Einstein relation in the mode-coupling theory of glasses [J].
Biroli, Giulio ;
Bouchaud, Jean-Philippe .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2007, 19 (20)