Nanoarchitectonics of MoS2 petals with 0D@2D carbon derivatives for integrated photocapacitor application

被引:3
作者
Arjunkumar, B. [1 ]
Keerthana, T. [1 ]
Ramalingam, Gopal [1 ]
Vetrivelan, V. [2 ]
Ragupathi, C. [3 ]
Mangalaraja, R. V. [4 ,5 ]
Alam, Mohammed Mujahid [6 ,7 ]
Anbukumaran, S. K. [8 ]
机构
[1] Alagappa Univ, Dept Nanosci & Technol, Quantum Mat Res Lab QMRL, Karaikkudi 630003, Tamil Nadu, India
[2] Govt Coll Engn, Dept Phys, Tiruchirappalli 620012, Tamil Nadu, India
[3] Sriram Coll Arts & Sci, Dept Chem, Tiruvallur 602024, India
[4] Univ Adolfo Ibaenez, Fac Engn & Sci, Diagonal Torres 2640, Santiago 7941169, Chile
[5] Univ Arturo Prat, Vicerrectoria Invest Innovac, Ave Arturo Prat 2120, Iquique 1110939, Chile
[6] King Khalid Univ, Coll Sci, Dept Chem, Abha 61413, Saudi Arabia
[7] King Khalid Univ, Res Ctr Adv Mat Sci RCAMS, Abha 61413, Saudi Arabia
[8] Saveetha Univ, Saveetha Inst Med & Tech Sci, Ctr Global Hlth Res, Chennai 602105, India
关键词
MoSS nanopetals; DSSC; Supercapcitor; Photocapacitor; HYDROTHERMAL SYNTHESIS; HIGH-EFFICIENCY; NICKEL-OXIDE; SOLAR; SUPERCAPACITOR; PERFORMANCE; DOTS; NANOSPHERES; NANOSHEETS; DEVICE;
D O I
10.1016/j.jallcom.2024.177622
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Photocapacitors are a breakthrough in energy storage and generation, storing and generating solar energy in several ways. Sustainable technology and satisfying the energy needs of a rapidly changing planet depend on their progress. A hydrothermal technique was used to synthesize carbon quantum dots-ornamental MoSS nanopetals on reduced graphene oxide (rGO). XRD, Raman, and XPS validated the hybrid nanomaterial's phase purity, composition, and oxidation state. Morphological research showed MoSS nanopetals producing a flowerlike structure with evenly dispersed carbon quantum dots on a thin, twisted sheet. As a counter electrode in dye-sensitized solar cells (DSSCs), this hybrid material increased efficiency by 6.7 % and photovoltaic characteristics. An asymmetric supercapacitor made from the hybrid material and activated carbon had 166.6 F/g specific capacitance at 5 mV/s and 81.5 % capacitance retention after 5000 charge-discharge cycles. The combined photocapacitor device, combining DSSC and supercapacitor, obtained 4.4 % overall efficiency and 34 % storage efficiency. The MoSS nanopetals-based electrode shows promise for photocapacitor applications, potentially improving future flexible and wearable technologies.
引用
收藏
页数:14
相关论文
共 60 条
[1]   Hydrothermally grown MoS2-flowers as low cost counter electrode material for dye sensitized solar cell and electrode modifier for electrochemical sensing of 4-chlorophenol [J].
Ahmad, Khursheed ;
Kim, Haekyoung .
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS, 2023, 295
[2]   Enhancing photovoltaic performance in dye-sensitized solar cells using nanostructured NiS/MoS2 composite counter electrodes [J].
Ayaz, Muhammad ;
Hijji, Mohammad ;
Alatawi, Ayshah S. ;
Namazi, M. A. ;
Ershath, M. I. Mohamed .
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2024, 173
[3]   Combination of Asymmetric Supercapacitor Utilizing Activated Carbon and Nickel Oxide with Cobalt Polypyridyl-Based Dye-Sensitized Solar Cell [J].
Bagheri, Narjes ;
Aghaei, Alireza ;
Ghotbi, Mohammad Yeganeh ;
Marzbanrad, Ehsan ;
Vlachopoulos, Nick ;
Haggman, Leif ;
Wang, Michael ;
Boschloo, Gerrit ;
Hagfeldt, Anders ;
Skunik-Nuckowska, Magdalena ;
Kulesza, Pawel. J. .
ELECTROCHIMICA ACTA, 2014, 143 :390-397
[4]   Supercapacitor behaviors of carbon quantum dots by green synthesis method from tea fermented with kombucha [J].
Baslak, Canan ;
Demirel, Serkan ;
Kocyigit, Adem ;
Alatli, Hamdiye ;
Yildirim, Murat .
MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2022, 147
[5]   Recent advances on the preparation and electrochemical analysis of MoS2-based materials for supercapacitor applications: A mini-review [J].
Bello, Ismaila Taiwo ;
Oladipo, Odunayo ;
Adedokun, Oluwaseun ;
Dhlamini, Simon Mokhotjwa .
MATERIALS TODAY COMMUNICATIONS, 2020, 25
[6]   Efficient Counter Electrode of MoS2-GO/PEDOT:PSS for Platinum-free, High Performance Dye Sensitized Solar Cells [J].
Chamatam Kasi Reddy, Arimakula ;
Neeraja, Velpula ;
Meenakshamma, Ambapuram ;
Gurulakshmi, Maddala ;
Gurubhasker, Mangala ;
Raghavender, Mitty ;
Pedda Venkata Subbaiah, Yearva .
CHEMISTRYSELECT, 2024, 9 (10)
[7]  
Chhowalla M, 2013, NAT CHEM, V5, P263, DOI [10.1038/nchem.1589, 10.1038/NCHEM.1589]
[8]   Redox active and electrically conducting cobalt telluride Nanorods/Poly(1-aminoanthraquinone) composite and photoactive Rose Bengal dye based photo-supercapacitor [J].
Das, Aparajita ;
Deshagani, Sathish ;
Ghosal, Partha ;
Deepa, Melepurath .
APPLIED MATERIALS TODAY, 2020, 19
[9]   Mesoporous perovskite solar cells and the role of nanoscale compact layers for remarkable all-round high efficiency under both indoor and outdoor illumination [J].
Di Giacomo, F. ;
Zardetto, V. ;
Lucarelli, G. ;
Cina, L. ;
Di Carlo, A. ;
Creatore, M. ;
Brown, T. M. .
NANO ENERGY, 2016, 30 :460-469
[10]   A molecular fluorophore in citric acid/ethylenediamine carbon dots identified and quantified by multinuclear solid-state nuclear magnetic resonance [J].
Duan, Pu ;
Zhi, Bo ;
Coburn, Luke ;
Haynes, Christy L. ;
Schmidt-Rohr, Klaus .
MAGNETIC RESONANCE IN CHEMISTRY, 2020, 58 (11) :1130-1138