Research progress on modification of Cu-SSZ-13 catalyst for denitration of automobile exhaust gas

被引：0
|
作者：
Wang J. [1 ]
Zhang J. [1 ]
Tang X. [2 ]
Liu J. [2 ]
Ju M. [2 ]
机构：
[1] School of Chemical Engineering, Hebei University of Technology, Tianjin
[2] College of Environmental Science and Engineering, Nankai University, Tianjin
来源：
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2023年 / 42卷 / 09期
关键词：
Cu-SSZ-13; hydrothermal deactivation; modification; NH[!sub]3[!/sub]-SCR; sulfur poisoning;
D O I：
10.16085/j.issn.1000-6613.2022-1932
中图分类号：
学科分类号：
摘要：
Cu-SSZ-13 is an excellent deNOx catalyst with CHA skeleton structure, and thus it possesses good application prospect in the field of vehicle exhaust deNOx and has been applied commercially in Europe. However, the hydrothermal deactivation and sulfur poisoning of Cu-SSZ-13 will cause serious damage to the CHA skeleton structure and active sites of Cu-SSZ-13 and has limited its development. In order to solve these problems, the modification of Cu-SSZ-13 catalyst has become the focus of current research. The recent research progress on the active sites of Cu-SSZ-13 catalyst and the mechanism of its deactivation caused by hydrothermal aging and sulfur poisoning were summarized. Also, the latest modification methods aimed at improving the catalytic activity and tolerance of Cu-SSZ-13, such as creating new nanostructures, constructing poisoning sacrifice sites, metal doping modification, were discussed, which provides a new thought for enhancing the catalytic performance and anti-poisoning performance of Cu-SSZ-13. Furthermore, the future development of Cu-SSZ-13 modification technology was prospected with the innovative idea of regulation of the active site by specific metal doping and novel preparation methods to control the type of ions in the zeolite. Finally, the essential problems to be solved in catalyst modification were discussed. © 2023 Chemical Industry Press. All rights reserved.
引用
收藏
页码：4636 / 4648
页数：12
相关论文
共 91 条
  • [51] PAOLUCCI Christopher, PAREKH Atish A, KHURANA Ishant, Et al., Catalysis in a cage: Condition-dependent speciation and dynamics of exchanged Cu cations in SSZ-13 zeolites, Journal of the American Chemical Society, 138, 18, pp. 6028-6048, (2016)
  • [52] LI Shihan, KONG Haiyu, ZHANG Weiping, A density functional theory modeling on the framework stability of Al-rich Cu-SSZ-13 zeolite modified by metal ions, Industrial & Engineering Chemistry Research, 59, 13, pp. 5675-5685, (2020)
  • [53] DINGEMANS G, TERLINDEN N M, VERHEIJEN M A, Et al., Controlling the fixed charge and passivation properties of Si(100)/ Al<sub>2</sub>O<sub>3</sub> interfaces using ultrathin SiO<sub>2</sub> interlayers synthesized by atomic layer deposition, Journal of Applied Physics, 110, 9, (2011)
  • [54] WU Huibin, ZHANG Bin, LIANG Haojie, Et al., Distance effect of Ni-Pt dual sites for active hydrogen transfer in tandem reaction, The Innovation, 1, 2, (2020)
  • [55] KIM Hyungjun, LEE Han-Bo-Ram, MAENG W-J., Applications of atomic layer deposition to nanofabrication and emerging nanodevices, Thin Solid Films, 517, 8, pp. 2563-2580, (2009)
  • [56] ZHANG Tao, SHI Juan, LIU Jian, Et al., Enhanced hydrothermal stability of Cu-ZSM-5 catalyst via surface modification in the selective catalytic reduction of NO with NH<sub>3</sub>, Applied Surface Science, 375, pp. 186-195, (2016)
  • [57] TIAN Heyuan, PING Yuan, ZHANG Yibo, Et al., Atomic layer deposition of silica to improve the high-temperature hydrothermal stability of Cu-SSZ-13 for NH<sub>3</sub> SCR of NO<sub>x</sub>, Journal of Hazardous Materials, 416, (2021)
  • [58] MA Yue, CHENG Songqi, WU Xiaodong, Et al., Improved hydrothermal durability of Cu-SSZ-13 NH<sub>3</sub>-SCR catalyst by surface Al modification: Affinity and passivation, Journal of Catalysis, 405, pp. 199-211, (2022)
  • [59] YUE Ying-Hong, TANG Yi, LIU Yi, Et al., Chemical liquid deposition zeolites with controlled pore-opening size and shape-selective separation of isomers, Industrial & Engineering Chemistry Research, 35, 2, pp. 430-433, (1996)
  • [60] HAN L P, CAI S X, GAO M, Et al., Selective catalytic reduction of NO<sub>x</sub> with NH<sub>3</sub> by using novel catalysts: State of the art and future prospects, Chemical Reviews, 119, 19, pp. 10916-10976, (2019)
12345678910