Surface modification of imide containing polymers II: Co-reactive groups

被引：0
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作者：
Verdianz, Thomas [1 ]
Simbürger, Horst [2 ]
Liska, Robert [1 ]
机构：
[1] Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163/MC, 1060 Vienna, Austria
[2] ELIN EBG Motoren GmbH, Elingasse 3, 8160 Weiz, Austria
来源：
European Polymer Journal | 2006年 / 42卷 / 04期
关键词：
This paper describes basic studies of the surface modification of polyimide covered wires for insulation of electrical machines. By introduction of surface reactive groups mechanical interlocking during the curing step should improve the life cycle. Kinetic analysis of ring opening reactions by aminolysis of low molecular model compounds for polyimides proved fast modification reactions under mild conditions. The co-reactivity of various functional groups with unsaturated polyesterimide; acrylate and epoxy resins was investigated by DSC. Aminolytic treatment of Kapton&reg sheets was followed by ATR-IR. Mandrel bend test of agglutinations of unmodified and amine-treated Kapton&reg sheets with different resins proved successful bonding and significantly improved adhesion. © 2005 Elsevier Ltd. All rights reserved;
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页码：869 / 882
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