On-surface synthesis of single-layered two-dimensional covalent organic frameworks via solid-vapor interface reactions

被引：0
|
作者：
机构：
[1] [1,Liu, Xuan-He
[2] 1,Guan, Cui-Zhong
[3] Ding, San-Yuan
[4] Wang, Wei
[5] Yan, Hui-Juan
[6] Wang, Dong
[7] Wan, Li-Jun
来源：
Wang, D. (wangd@iccas.ac.cn) | 1600年 / American Chemical Society卷 / 135期
关键词：
Surface covalent organic frameworks (SCOFs); featured by atomic thick sheet with covalently bonded organic building units; are promised to possess unique properties associated with reduced dimensionality; well-defined in-plane structure; and tunable functionality. Although a great deal of effort has been made to obtain SCOFs with different linkages and building blocks via both top-down exfoliation and bottom-up surface synthesis approaches; the obtained SCOFs generally suffer a low crystallinity; which impedes the understanding of intrinsic properties of the materials. Herein; we demonstrate a self-limiting solid-vapor interface reaction strategy to fabricate highly ordered SCOFs. The coupling reaction is tailored to take place at the solid-vapor interface by introducing one precursor via vaporization to the surface preloaded with the other precursor. Following this strategy; highly ordered honeycomb SCOFs with imine linkage are obtained. The controlled formation of SCOFs in our study shows the possibility of a rational design and synthesis of SCOFs with desired functionality. © 2013 American Chemical Society;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
相关论文
共 50 条
  • [31] Vinylene-Bridged Two-Dimensional Covalent Organic Frameworks via Knoevenagel Condensation of Tricyanomesitylene
    Bi, Shuai
    Thiruvengadam, Palani
    Wei, Shice
    Zhang, Wenbei
    Zhang, Fan
    Gao, Lusha
    Xu, Junsong
    Wu, Dongqing
    Chen, Jie-Sheng
    Zhang, Fan
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (27) : 11893 - 11900
  • [32] Growing single crystals of two-dimensional covalent organic frameworks enabled by intermediate tracing study
    Chengjun Kang
    Kuiwei Yang
    Zhaoqiang Zhang
    Adam K. Usadi
    David C. Calabro
    Lisa Saunders Baugh
    Yuxiang Wang
    Jianwen Jiang
    Xiaodong Zou
    Zhehao Huang
    Dan Zhao
    Nature Communications, 13
  • [33] Growing single crystals of two-dimensional covalent organic frameworks enabled by intermediate tracing study
    Kang, Chengjun
    Yang, Kuiwei
    Zhang, Zhaoqiang
    Usadi, Adam K.
    Calabro, David C.
    Baugh, Lisa Saunders
    Wang, Yuxiang
    Jiang, Jianwen
    Zou, Xiaodong
    Huang, Zhehao
    Zhao, Dan
    NATURE COMMUNICATIONS, 2022, 13 (01)
  • [34] Hierarchical On-Surface Synthesis of Two-Dimensional Networks via S•••N and S•••H
    Shu, Chen-Hui
    Kang, Li-Xia
    Wang, Shan-shan
    He, Yan
    Zhang, Ruo-Xi
    Su, Xuelei
    Yu, Ping
    Li, Xingguang
    Liu, Pei-Nian
    CCS CHEMISTRY, 2025, 7 (01): : 170 - 179
  • [35] Structurally precise synthesis of two-dimensional covalent organic frameworks and linear polymers for optoelectronics and therapeutics
    Colson, John
    Dichtel, William
    Mulzer, Catherine
    Mann, Jason
    Hubbell, Jeffrey
    Wang, Ruyi
    Wilson, D.
    Nagler, Cathryn
    Plunkett, Catherine
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 254
  • [36] Solvent-Free Synthesis of C=N Linked Two-Dimensional Covalent Organic Frameworks
    Zhang, Yushu
    Mao, Tianhui
    Hao, Liqin
    Sun, Tiankai
    Wang, Tonghai
    Cheng, Peng
    Chen, Yao
    Wang, Zhifang
    Zhang, Zhenjie
    MACROMOLECULAR RAPID COMMUNICATIONS, 2023, 44 (11)
  • [37] Flexible Solid Electrolytes from Two-Dimensional Metal Carbide, Polymer, and Ionic Covalent Organic Frameworks
    Serajian, Sahand
    Mohamed, Syed Ibrahim Gnani Peer
    Shaban, Mahmoud M.
    Voigt, Jacob
    Quirie, Micah
    Morton, Martha
    Nejati, Siamak
    Bavarian, Mona
    ACS APPLIED ENGINEERING MATERIALS, 2024, 3 (01): : 64 - 74
  • [38] Single-Layered Two-Dimensional Metal-Organic Framework Nanosheets as an in Situ Visual Test Paper for Solvents
    Luo, Yang-Hui
    Chen, Chen
    He, Chang
    Zhu, Ying-Yu
    Hong, Dan-Li
    He, Xiao-Tong
    An, Pei-Jing
    Wu, Hong-Shuai
    Sun, Bai-Wang
    ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (34) : 28860 - 28867
  • [39] Control Interlayer Stacking and Chemical Stability of Two-Dimensional Covalent Organic Frameworks via Steric Tuning
    Liu, Yan (liuy@sjtu.edu.cn), 1600, American Chemical Society (140):
  • [40] Control Interlayer Stacking and Chemical Stability of Two-Dimensional Covalent Organic Frameworks via Steric Tuning
    Wu, Xiaowei
    Han, Xing
    Liu, Yuhao
    Liu, Yan
    Cui, Yong
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (47) : 16124 - 16133
12345