Coupling Photocatalytic Hydrogen Production with Key Oxidation Reactions

被引：45

作者：

Teng, Jiayan ^{[1
]}

Li, Wenlu ^{[2
,3
]}

Wei, Zhen ^{[1
]}

Hao, Derek ^{[4
,5
]}

Jing, Lin ^{[1
]}

Liu, Yuxi ^{[1
]}

Dai, Hongxing ^{[1
]}

Zhu, Yongfa ^{[2
]}

Ma, Tianyi ^{[4
,5
]}

Deng, Jiguang ^{[1
]}

机构：

[1] Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Key Lab Adv Funct Mat,Educ Minist China, Beijing 100124, Peoples R China

[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

[3] Beijing Technol & Business Univ, Sch Food & Hlth, Beijing 100048, Peoples R China

[4] RMIT Univ, Ctr Atomaterials & Nanomfg CAN, Sch Sci, Melbourne 3000, Australia

[5] ARC Ind Transformat Res Hub Intelligent Energy Eff, Melbourne 3000, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2024年 / 63卷 / 50期

基金：

中国国家自然科学基金; 澳大利亚研究理事会;

关键词：

Photocatalysis; Hydrogen Production; Water Splitting; Coupling Reactions; GRAPHITIC CARBON NITRIDE; QUANTUM EFFICIENCY; ENERGY-CONVERSION; WATER; DRIVEN; WASTE; BIOMASS; LIGNIN; TRANSFORMATION; VALORIZATION;

D O I：

10.1002/anie.202416039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydrogen represents a clean and sustainable energy source with wide applications in fuel cells and hydrogen energy storage systems. Photocatalytic strategies emerge as a green and promising solution for hydrogen production, which still reveals several critical challenges in enhancing the efficiency and stability and improving the whole value. This review systematically elaborates on various coupling approaches for photocatalytic hydrogen production, aiming to improve both efficiency and value through different oxidation half-reactions. Firstly, the fundamental mechanism is discussed for photocatalytic hydrogen production. Then, the advances, challenges, and opportunities are expanded for the coupling of photocatalytic hydrogen production, which focuses on the integration of value-added reactions including O2 production, H2O2 production, biomass conversion, alcohol oxidation, and pollutants treatment. Finally, the challenges and outlook of photocatalytic H2 production technology are analyzed from the aspects of coupling hydrogen production value, photocatalyst design and reaction system construction. This work presents a holistic view of the field, emphasizing the synergistic benefits of coupled reactions and their practical application potential, rather than focusing on catalysts or single reaction systems. This review provides valuable references for the development and application of photocatalytic hydrogen production in energy conversion and environmental conservation through sustainable, eco-friendly and economic pathways.

引用

页数：19

共 134 条

[1] Metal Single-Atom Cocatalyst on Carbon Nitride for the Photocatalytic Hydrogen Evolution Reaction: Effects of Metal Species [J].

Akinaga, Yuki ;

Kawawaki, Tokuhisa ;

Kameko, Hinano ;

Yamazaki, Yuki ;

Yamazaki, Kenji ;

Nakayasu, Yuhi ;

Kato, Kosaku ;

Tanaka, Yuto ;

Hanindriyo, Adie Tri ;

Takagi, Makito ;

Shimazaki, Tomomi ;

Tachikawa, Masanori ;

Yamakata, Akira ;

Negishi, Yuichi .

ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (33)

[2] Photocatalytic Selective Oxidation of HMF Coupled with H2 Evolution on Flexible Ultrathin g-C3N4 Nanosheets with Enhanced N-H Interaction [J].

Bao, Xiaolei ;

Liu, Mu ;

Wang, Zeyan ;

Dai, Dujuan ;

Wang, Peng ;

Cheng, Hefeng ;

Liu, Yuanyuan ;

Zheng, Zhaoke ;

Dai, Ying ;

Huang, Baibiao .

ACS CATALYSIS, 2022, 12 (03) :1919-1929

[3] PHOTOELECTROCHEMISTRY AND HETEROGENEOUS PHOTOCATALYSIS AT SEMICONDUCTORS [J].

BARD, AJ .

JOURNAL OF PHOTOCHEMISTRY, 1979, 10 (01) :59-75

[4] Photocatalytic pure water splitting with high efficiency and value by Pt/porous brookite TiO2 nanoflutes [J].

Cao, Shuang ;

Chan, Ting-Shan ;

Lu, Ying-Rui ;

Shi, Xinghua ;

Fu, Bing ;

Wu, Zhijiao ;

Li, Hongmei ;

Liu, Kang ;

Alzuabi, Sarah ;

Cheng, Ping ;

Liu, Min ;

Li, Tao ;

Chen, Xiaobo ;

Piao, Lingyu .

NANO ENERGY, 2020, 67

[5] Atomic-Level Charge Separation Strategies in Semiconductor-Based Photocatalysts [J].

Chen, Fang ;

Ma, Tianyi ;

Zhang, Tierui ;

Zhang, Yihe ;

Huang, Hongwei .

ADVANCED MATERIALS, 2021, 33 (10)

[6] Particulate metal chalcogenides for photocatalytic Z-scheme overall water [J].

Chen, Shanshan ;

Li, Chenyang ;

Domen, Kazunari ;

Zhang, Fuxiang .

JOULE, 2023, 7 (11) :2445-2467

[7] Effect of Rh oxide as a cocatalyst over Bi0.5Y0.5VO4 on photocatalytic overall water splitting [J].

Chen, Wei ;

Yang, Bingbing ;

Yu, Qingtao ;

Mao, Liqun ;

Fan, Zeyun ;

Wang, Qizhao ;

Shangguan, Wenfeng .

APPLIED SURFACE SCIENCE, 2015, 355 :1069-1074

[8] Efficient Photocatalytic Overall Water Splitting Induced by the Giant Internal Electric Field of a g-C3N4/rGO/PDIP Z-Scheme Heterojunction [J].

Chen, Xianjie ;

Wang, Jun ;

Chai, Yongqiang ;

Zhang, Zijian ;

Zhu, Yongfa .

ADVANCED MATERIALS, 2021, 33 (07)

[9] Three-dimensional porous g-C3N4 for highly efficient photocatalytic overall water splitting [J].

Chen, Xianjie ;

Shi, Run ;

Chen, Qian ;

Zhang, Zijian ;

Jiang, Wenjun ;

Zhu, Yongfa ;

Zhang, Tierui .

NANO ENERGY, 2019, 59 :644-650

[10] Achieving simultaneous hydrogen evolution and organic pollutants degradation through the modification of Ag3PO4 using Cs2AgBiBr6 quantum dots and graphene hydrogel [J].

Chen, Zhuo ;

Li, Xiaoming ;

Wu, You ;

Duan, Abing ;

Wang, Dongbo ;

Yang, Qi ;

Fan, Yingchun .

SEPARATION AND PURIFICATION TECHNOLOGY, 2022, 302

← 1 2 3 4 5 6 7 8 9 10 →