The Effect of Laponite on the Structure, Mechanical and Thermal Properties of Poly(butylene Succinate)

被引:0
作者
Malinowski, Rafal [1 ]
Krasinskyi, Volodymyr [1 ]
Moraczewski, Krzysztof [2 ]
Raszkowska-Kaczor, Aneta [1 ]
Grytsenko, Oleksandr [3 ]
Moravskyi, Volodymyr [3 ]
Miklaszewski, Andrzej [4 ]
机构
[1] Lukasiewicz Res Network, Inst Engn Polymer Mat & Dyes, 55 M Sklodowska Curie St, PL-87100 Torun, Poland
[2] Kazimierz Wielki Univ, Fac Mat Engn, 30 Chodkiewicza St, PL-85064 Bydgoszcz, Poland
[3] Lviv Polytech Natl Univ, Dept Chem Technol Plast Proc, 12 Bandera St, UA-79013 Lvov, Ukraine
[4] Poznan Univ Tech, Inst Mat Sci & Engn, 24 Jana Pawla 2 St, PL-60965 Poznan, Poland
关键词
poly(butylene succinate); Laponite; composites; mechanical properties; thermal properties; extrusion; BIODEGRADABLE ALIPHATIC POLYESTERS; MULTIPLE MELTING BEHAVIOR; CRYSTALLIZATION; HECTORITE; PERFORMANCE; COMPOSITES;
D O I
10.3390/polym16223186
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The comparison of some changes occurring in the physical properties of poly(butylene succinate) (PBS) due to its modification with Laponite (LAP) was the objective of this study. The PBS composites, containing from 1 to 7 wt% LAP, were prepared by co-rotating twin screw extrusion. The geometrical surface structure of the samples' fractures and the LAP content in the individual composites were examined. In addition, changes in the mechanical and thermal properties, melt flow rate and moisture sorption of the composites were studied. It was found that LAP increases the elastic modulus of PBS and also decreases its impact strength and, in particular, its strain. The strength of PBS changes to a lesser extent with an increase in the LAP content, i.e., it slightly decreases in tensile tests or slightly increases in bending tests. LAP also lowers the flow rate of PBS and significantly increases moisture sorption. Moreover, the composites produced were characterized by a uniform distribution of the dispersed phase in the polymer matrix and an acceptable adhesion at the interface between the two components.
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页数:13
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