Baeyer-Viiliger Oxidation of Cyclic Ketones Using Aqueous Hydrogen Peroxide Catalyzed by Heteropolyacids in Solvent-free System

被引：1

作者：

Ma, Qingguo ^{[1
]}

Zhao, Jingru ^{[1
]}

Xing, Wanzhen ^{[1
]}

Peng, Xinhua ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Jiangsu, Peoples R China

来源：

JOURNAL OF ADVANCED OXIDATION TECHNOLOGIES | 2014年 / 17卷 / 02期

关键词：

heteropolyacids; Baeyer-Villiger oxidation; cyclic ketone; hydrogen peroxide; VILLIGER OXIDATION; ACID; ESTERIFICATION; EFFICIENT; ZEOLITES; BETA;

D O I：

10.1515/jaots-2014-0206

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The conversion of cyclic ketones to lactones was catalyzed by different acid catalysts using aqueous hydrogen peroxide (30 wt%) as a clean oxidant. H3PW12O40 seems to be a rather efficient and highly selective catalyst for the Baeyer-Villiger reaction of 2-heptylcyclopentanone and 2-adamantanone to lactones. For cyclopentanone, cyclohexanone, cycloheptanone and cyclododecanone, the selectivity for lactones was very poor, but selectivity for acids was high.

引用

页码：212 / 216

页数：5