Two dimensional chiral networks emerging from the aryl-FH hydrogen-bond-driven self-assembly of partially fluorinated rigid molecular structures

被引：0
|
作者：
Mu, Zhongcheng [1 ]
Shu, Lijin [2 ]
Fuchs, Harald [1 ]
Mayor, Marcel [2 ,3 ]
Chi, Lifeng [1 ]
机构：
[1] Physikalisches Institut, Westfälische Wilhelms-Universität Münster, Wilhelm-Klemm-Str. 10, 48149 Münster, Germany
[2] Institute for Nanotechnology, Forschungszentrum Karlsruhe GmbH, Postfach 3640, 76021 Karlsruhe, Germany
[3] Department of Chemistry, University of Basel, St. Johannsring 19, 4056 Basel, Switzerland
来源：
Journal of the American Chemical Society | 2008年 / 130卷 / 33期
关键词：
Self-assembly of the partially fluorinated rigid molecules physisorbed at solution/graphite interface has been investigated by scanning tunneling microscopy. Upon adsorption; both the branched star-shaped compound 1 and the angulate rod 2 compromising diacetylene and acetylene interlinked benzene and pentafluorobezene formed two-dimensional chiral porous networks. The spontaneous formation of these architectures is likely attributed to the two effects: the compensation of the dipole moments of the branches and the formation of Ar-HF hydrogen bonds. These results demonstrate that the immobilization of molecules at the liquid/solid interface can be driven by these weak intermolecular interactions instead of van der Waals interactions between alkyl chains and substrate. Copyright © 2008 American Chemical Society;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：10840 / 10841
相关论文
共 10 条
  • [1] Two dimensional chiral networks emerging from the aryl-F... H hydrogen-bond-driven self-assembly of partially fluorinated rigid molecular structures
    Mu, Zhongcheng
    Shu, Lijin
    Fuchs, Harald
    Mayor, Marcel
    Chi, Lifeng
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (33) : 10840 - +
  • [2] Development of simulation approach for two-dimensional chiral molecular self-assembly driven by hydrogen bond at the liquid/solid interface
    Qin, Yuan
    Yao, Man
    Hao, Ce
    Wan, Lijun
    Wang, Yunhe
    Che, Ting
    Wan, Dong
    Wang, Xudong
    Chen, Yonggang
    SURFACE SCIENCE, 2017, 663 : 71 - 80
  • [3] Self-assembly of two-dimensional structures in water from rigid and curved amphiphiles with a low molecular weight
    Yao, Huan
    Yang, Liu-Pan
    Pang, Xin-Yu
    Li, Jia-Rong
    Jiang, Wei
    CHEMICAL COMMUNICATIONS, 2018, 54 (77) : 10847 - 10850
  • [4] Two-dimensional porphyrin networks: From nucleobase driven self-assembly to covalent-organic frameworks
    Blunt, Matthew
    Nowicka-Dylag, Caroline
    Hu, Ya
    Goodeal, Niall
    Ganose, Alex
    Slater, Anna
    Palgrave, Robert
    Toft, Charles
    Lewis, William
    Bronstein, Hugo
    Champness, Neil
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 257
  • [5] Self-Assembly from Two-Dimensional Layered Networks to Tetranuclear Structures: Syntheses, Structures, and Properties of Four Copper-Thiacalix[4]arene Compounds
    Bi, Yanfeng
    Liao, Wuping
    Wang, Xinwu
    Deng, Ruiping
    Zhang, Hongjie
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (33) : 4989 - 4994
  • [6] Hydrogen-Bond Driven Self-Assembly of Two-Dimensional Supramolecular Melamine-Cyanuric Acid Crystals and Its Self-Alignment in Polymer Composites for Enhanced Thermal Conduction
    Mehra, Nitin
    Jeske, Madelyn
    Yang, Xutong
    Gu, Junwei
    Kashfipour, Marjan Alsadat
    Li, Yifan
    Baughman, Jessi Alan
    Zhu, Jiahua
    ACS APPLIED POLYMER MATERIALS, 2019, 1 (06): : 1291 - +
  • [7] Coordination-driven chiral self-assembly: Synthesis, structures and vapor adsorption properties of Zn(II) and Ag(I) complexes derived from two helical pyridylamide ligands
    Li, Rong-Feng
    Zhu, Jun-Xia
    Jia, Wei-Dong
    Lu, Ding-Jie
    Huang, Chao
    Zhu, Bi-Xue
    INORGANIC CHEMISTRY COMMUNICATIONS, 2022, 145
  • [8] Self-assembly of a chiral phosphinegold(I) building block into a two-dimensional netsheet based on a hydrogen bond between one Cl- anion and three hydroxy groups, co-ordination and aurophilicity interactions
    Shi, JC
    Kang, BS
    Mak, TCW
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (12): : 2171 - 2175
  • [9] Synthesis, structures and properties of two-dimensional honeycomb and stepwise networks from self-assembly of tripodal ligand 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene with metal salts
    Fan, J
    Sui, B
    Okamura, T
    Sun, WY
    Tang, WX
    Ueyama, N
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (20): : 3868 - 3873
  • [10] Three-dimensional supramolecular assembly having infinite two-dimensional interlocking networks built up only from simple and non-rigid organic molecules via hydrogen bonds.: Crystal structures of α,ω-diureidoalkanes H2N(CO)NH-(CH2)n-NH(CO)NH2with n=4 and 5
    Eda, K
    Okazaki, T
    Yamamura, K
    Hashimoto, M
    JOURNAL OF MOLECULAR STRUCTURE, 2005, 752 (1-3) : 93 - 97
1