Electrocatalytic Bipolar Synthesis of Valuable Chemicals

被引：3

作者：

Gao, Wenqi ^{[1
,2
,3
,4
]}

Wang, Chen ^{[1
,2
,3
,4
]}

Lv, Lin ^{[1
,2
,3
,4
]}

Yan, Dafeng ^{[1
,2
,3
,4
]}

Xia, Bao Yu ^{[5
]}

机构：

[1] Hubei Univ, Hubei Key Lab Precis Synth Small Mol Pharmaceut, 368 Youyi Rd, Wuhan 430062, Peoples R China

[2] Hubei Univ, Key Lab Synth & Applicat Organ Funct Mol, Minist Educ, 368 Youyi Rd, Wuhan 430062, Peoples R China

[3] Hubei Univ, Coll Chem & Chem Engn, 368 Youyi Rd, Wuhan 430062, Peoples R China

[4] Hubei Univ, Sch Microelect, 368 Youyi Rd, Wuhan 430062, Peoples R China

[5] Huazhong Univ Sci & Technol HUST, Sch Chem & Chem Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan Natl Lab Optoelect,Key Lab Mat Chem Energy C, 1037 Luoyu Rd, Wuhan 430074, Peoples R China

来源：

CHEMCATCHEM | 2024年 / 16卷 / 21期

基金：

中国国家自然科学基金;

关键词：

Electrosynthesis; Electrocatalytic bipolar synthesis; Reaction mechanism; Electrocatalysis; FORMALDEHYDE OXIDATION; HYDROGEN-PRODUCTION; CO2; REDUCTION; CONVERSION; PERFORMANCE; CATALYSTS; ELECTROSYNTHESIS; AMMONIA; SURFACE; OXYGEN;

D O I：

10.1002/cctc.202401198

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electrocatalysis can synthesize kinds of valuable chemicals and plays vital role in developing clean and renewable energy storage and conversion devices. In the traditional electrocatalytic systems, researchers try to synthesize one type of valuable chemical at cathode or anode independently. Recently, electrocatalytic bipolar synthesis of valuable chemicals at both cathode and anode simultaneously becomes popular and attracts much attention. In this minireview, we summarize the latest processes on innovative strategies for electrocatalytic bipolar synthesis of various chemicals. We will discuss the findings according to the categories of the products, including bipolar hydrogen production, bipolar formate production and bipolar hydrogenation. And the associated catalysts optimization, reaction mechanism, and design principles are well introduced. Moreover, the challenges and prospects are highlighted for future developments. This review is timely and will guide others pay more attention to this novel electrocatalytic bipolar synthesis systems.

引用

页数：12

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