Characteristics of organic light emitting diodes with tetrakis(Ethylmethylamino) hafnium treated indium tin oxide

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作者
Sohn, Sunyoung [1 ]
Park, Keunhee [1 ]
Jung, Donggeun [1 ]
Kim, Hyoungsub [2 ]
Chae, Heeyeop [3 ]
Kim, Hyunmin [4 ]
Yi, Junsin [4 ]
Cho, Mann-Ho [5 ]
Boo, Jin-Hyo [6 ]
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[1] Department of Physics, Institute of Basic Science, and Brain, Sungkyunkwan University, Suwon 440-746, Korea, Republic of
[2] School of Advanced Materials Science and Engineering, Sungkyunkwan University, Suwon 440-746, Korea, Republic of
[3] Department of Chemical Engineering, Sungkyunkwan University, Suwon 440-746, Korea, Republic of
[4] School of Information and Communication Engineering, Sungkyunkwan University, Suwon 440-746, Korea, Republic of
[5] Institute of Physics and Applied Physics, Yonsei University, 134 Shinchon-Dong, Seodaemun-Ku, Seoul 120-729, Korea, Republic of
[6] Department of Chemistry, Institute of Basic Science, and Brain, Sungkyunkwan University, Suwon 440-746, Korea, Republic of
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The surface of indium tin oxide (ITP) in organic light emitting diodes (PLEDs) was treated using an atomic layer deposition with tetrakis(ethylmethylamino) hafnium (TEMAH) and O2 precursors. The treatment for 5 cycles at room temperature resulted in a significant improvement in the electroluminescent characteristics resulting from the increased hole injection. According to the various characterizations; an ultra-thin HfO x layer without any insulating properties was formed; which modified the electronic band structure of the ITP anode. When the number of cycles or temperature was increased; an electrically insulating HfOx was formed; and the resulting PLED properties deteriorated. ©2007 The Japan Society of Applied Physics;
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