Removal of 1,3-dichloro-2-propanol and 3-chloro-1,2-propanediol by the whole cell system of pseudomonas putida DSM 437

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作者
Mamma, Diomi [1 ]
Papadopoulou, Eleni [1 ]
Petroutsos, Dimitris [1 ]
Christakopoulos, Paul [1 ]
Kekos, Dimitris [1 ]
机构
[1] Biotechnology Laboratory, School of Chemical Engineering, National Technical University of Athens, 157 80 Zografou, Greece
来源
Journal of Environmental Science and Health - Part A Toxic/Hazardous Substances and Environmental Engineering | 2006年 / 41卷 / 03期
关键词
The removal of 1,3-dichloro-2-propanol (1,3-DCP), 3-chloro-1,2-propanediol (3-CPD) and their mixtures at concentrations up to 1000 mg&middotL-1 by the whole cell system of Pseudomonas putida DSM 437 was investigated. The 1,3-DCP removal rates ranged from 2.36 to 10.55 mg&middotL -1&middoth-1; 3-CPD exhibited approximately two times higher removal rates compared to 1,3-DCP for all concentrations tested. Removal of 1,3-DCP and 3-CPD followed first-order kinetics with rate constants of 0.0109 h-1 and 0.0206 h-1, respectively. When the whole cell system of P. putida DSM 437 was applied to mixtures of the two halohdrins, complete removal of 1,3-DCP was achieved at 144 h while removal of 3-CPD was completed at times ranging from 72 to 144 h. Time to achieve 50% removal of both halohydrins depends on the initial concentration of each in the mixture. For 1,3-DCP, it ranged from 40.55 h at 200 mg&middotL-1 to 53.28 h at 500 mg&middotL-1 while the respected values for 3-CPD were 33.39 and 68.91 h. Copyright © Taylor & Francis Group, LLC;
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页码:303 / 313
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