Solid-state 207Pb nuclear magnetic resonance studies of adducts of 1,10-phenanthroline with lead(II) halides

被引：0
|
作者：
Glatfelter A. [1 ]
Bai S. [1 ]
Dmitrenko O. [1 ]
Perry D.L. [2 ]
Van Bramer S.E. [3 ]
Dybowski C. [1 ]
机构：
[1] Department of Chemistry and Biochemistry, University of Delaware, Newark
[2] Lawrence Berkeley National Laboratory, Berkeley
[3] Department of Chemistry, Widener University, Chester
来源：
Canadian Journal of Chemistry | 2011年 / 89卷 / 07期
基金：
美国国家科学基金会;
关键词：
1,10-phenanthroline; !sup]207[!/sup]Pb NMR; Density functional theory; Lead(II) bromide; Lead(II) iodide; Solid-state NMR; Zeroth-order regular approximation (ZORA);
D O I：
10.1139/v10-176
中图分类号：
学科分类号：
摘要：
Experimental and predicted 207Pb nuclear magnetic resonance (NMR) parameters of solid-state coordination complexes of lead(II) bromide, lead(II) iodide, and lead(II) chloride with 1,10-phenanthroline are reported. Structural and electronic differences between the 1:1 and 1:2 adducts are reflected by the NMR parameters. The NMR chemical shieldings of the isostructural complexes indicate that the electronic state of the lead(II) center depends on the number of ligands and the halogen anion. The NMR results suggest that the 1:2 adduct may be more stereochemically active than the 1:1 adduct. © 2011 Published by NRC Research Press.
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收藏
页码：863 / 869
页数：6
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