Effects of nano-SiO2 and nano-CaCO3 on properties of ultra-high performance cementitious composites

被引:10
作者
Rong, Zhidan [1 ]
Jiang, Guang [1 ]
Sun, Wei [1 ]
机构
[1] Jiangsu Key Laboratory of Construction Materials, Southeast University, Nanjing
来源
Dongnan Daxue Xuebao (Ziran Kexue Ban)/Journal of Southeast University (Natural Science Edition) | 2015年 / 45卷 / 02期
关键词
Microstructure; Nano-CaCO[!sub]3[!/sub; Nano-SiO[!sub]2[!/sub; Nanoindentation; Ultra-high performance cementitious composite;
D O I
10.3969/j.issn.1001-0505.2015.02.034
中图分类号
学科分类号
摘要
The effects of nano-SiO2 and nano-CaCO3 on the mechanical performance of ultra high performance cementitious composite (UHPCC) were studied. The hydration process and microstructure of UHPCC were investigated via hydration heat analysis method, XRD(X-ray diffraction), MIP(mercury intrusion porosimetry), nanoindentation and other analysis testing methods. The results indicate that the mechanical performance is improved by adding nano-SiO2 and nano-CaCO3. The optimal content of nano-CaCO3 is about 3% to 5%. With high chemical reactivity, nano-SiO2 promotes the early-age hydration process in cement, reacting with Ca(OH)2 to form C-S-H gel. The nano-CaCO3 phases may fill up void spaces and act as nucleation sites. As a result, the composites structure can be condensed significantly with the decrease of porosity and pore size. More hydrated products of UHPCC lead to formation of ultra high density(UHD) C-S-H which strengthens the interface zones. The UHPCC has excellent mechanical performance due to its compact microstructure. ©, 2015, Southeast University. All right reserved.
引用
收藏
页码:393 / 398
页数:5
相关论文
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