Iodine- and nitrogen-CO-doped carbon flower materials for the anode electrode of lithium-ion batteries

被引:0
作者
Li, Ying [1 ]
Zhao, Yaxin [1 ]
Liu, Ruifeng [1 ]
Zhang, Luyao [1 ]
Zhang, Junzhe [1 ]
Hu, Xinlong [1 ]
Lei, Fang [1 ]
Wang, Huiqi [1 ]
机构
[1] North Univ China, Sch Mat Sci & Engn & Energy & Power Engn, Lab Coal based Carbon Dots & Carbon Reduced Techno, Res Grp New Energy Mat & Devices, Taiyuan 030051, Peoples R China
基金
中国国家自然科学基金;
关键词
Anode material; carbon; iodine and nitrogen co-doping; flower-like structure; lithium-ion batteries; GRAPHENE; CONDUCTIVITY; PERFORMANCE;
D O I
10.1142/S179360472451038X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
As green anode materials with wide distribution, controllable cost, and diversified structure, carbon materials have received more attention. In this paper, iodine- and nitrogen-co-doped carbon flower materials were prepared. The flower-like structure of the material ensures the rapid diffusion of lithium ions, and the synergistic effect of iodine and nitrogen atoms improves the pore size distribution, the conductivity and the active sites of carbon materials realizing the high ion storage and the fast charge diffusion. As the anode material of lithium-ion batteries, the iodine- and nitrogen-co-doped carbon flower could have the capacitance of 410 mAh g(-1) at the current density of 0.1 A g(-1) after 150 cycles and 181 mAh g(-1) at the high current density of 2.0 A g(-1) after 1000 cycles. The results of electrochemical impedance spectroscopy, kinetics, and GITT show this material has fast charge transport kinetics and excellent rate performance.
引用
收藏
页数:8
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