Forced to align: Flow-induced long-range alignment of hierarchical molecular assemblies from 2D to 3D

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[1] Lee, Shern-Long
[2] Yuan, Zhongyi
[3] Chen, Long
[4] Mali, Kunal S.
[5] Müllen, Klaus
[6] De Feyter, Steven
来源：
Mali, K.S. (kunal.mali@chem.kuleuven.be) | 1600年 / American Chemical Society卷 / 136期
关键词：
Nanostructured molecular thin films adsorbed on solid surfaces form the basis of numerous applications. Long-range order within adsorbed molecules is very often a desirable property for such systems. In this contribution; we report a simple and efficient method to fabricate well-aligned thin films of organic molecules over a few millimeter squares. The strategy involves use of capillary force in a two-step flow method to induce large-area alignment of multilayers of molecules at the organic liquid-solid interface. Furthermore; we also demonstrate the influence of alignment on the electron transport through these well-aligned thin films using scanning tunneling spectroscopy. © 2014 American Chemical Society;
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