CPAM-assisted synthesis of NaA zeolite membrane on macroporous mullite hollow fiber for ethanol dehydration by pervaporation

被引:0
|
作者
Tang, Liqin [1 ]
Jin, Xiang [1 ]
Gao, Bing [1 ]
Gao, Xuechao [1 ]
Gu, Xuehong [1 ]
机构
[1] Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, 30 South Puzhu Rd, Nanjing 211816, Peoples R China
来源
CHINESE JOURNAL OF CHEMICAL ENGINEERING | 2025年 / 77卷
基金
中国国家自然科学基金;
关键词
CPAM-Modification; NaA zeolite membranes; Mullite hollow fiber; Seeding; Pervaporation; FACILE SYNTHESIS; SECONDARY GROWTH; LIGHT GASES; SUPPORTS; TRANSPORT; CRYSTALS; SILICA; MODULE; WATER; GLASS;
D O I
10.1016/j.cjche.2024.09.016
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Due to the low transport resistance, mullite hollow fiber (HF) could be regarded as a promising support for preparation of NaA zeolite membranes. However, insufficient coverage and undesired seed penetration often occur in the seeding step of the mullite support due to the rough surfaces with ultra-large macropores (2-4 mm). This leads to poor intergrowth of the membrane layer. To solve this issue, cationic polyacrylamide (CPAM) was employed to modify the chemical and electrostatic properties of the mullite HF surface, where the electrostatic attraction between the surface and seed crystals could significantly promote the coating effect. In the seeding, the original seeds (3.2 mm) were mixed with the ball-milled seeds (0.3 mm) to improve the seed coverage, i.e., the original seed was used to block the macropores on the support surface to prevent the penetration of small seeds, while the decked ball-milled seed was used to provide sufficient active sites to induce the intergrowth of the zeolite crystals. The effects of the concentration of CPAM, mixed mass ratio of seeds, and seed concentration on the preparation of NaA zeolite membranes were systematically examined, where the separation performances were characterized by pervaporation (PV) dehydration of 90% (mass) ethanol/water mixtures at 75 degrees C. The results indicated that under a CPAM concentration of 0.7% (mass), an equivalent mass ratio of mixed seeds in a seed concentration of 1.0% (mass), the prepared mullite HF supported NaA zeolite membrane yielded the best PV performance, where the permeation flux and separation factor corresponded to 5.45 kg center dot m(-2)center dot h(-1) and 10000, respectively, being sufficient for industrial applications. (c) 2024 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights are reserved, including those for text and data mining, AI training, and similar technologies.
引用
收藏
页码:66 / 80
页数:15
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