Photocatalytic degradation of Rose Bengal using a Z-scheme NiFe2O4/α-Fe2O3 heterojunction composite obtained by the Pechini method

被引:0
|
作者
Galvez-Barbosa, S. [1 ]
Gonzalez, Luis A. [2 ]
机构
[1] Univ Michoacana, Inst Invest Met & Mat, Ave Francisco J Muj S-N,Ciudad Univ, Morelia 58030, Michoacan, Mexico
[2] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Ave Ind Metalurg 1062, Ramos Arizpe 25900, Coahuila, Mexico
关键词
Pechini method; Z-scheme; Heterojunction; Photocatalytic; Rose Bengal; NIFE2O4;
D O I
10.1016/j.matlet.2024.137898
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study investigates the relationship between the concentration ratios of Fe:Ni wt% of 60.5:39.5 and 70.5:29.5 in the synthesis of NiFe2O4/alpha-Fe2O3 heterojunction composites (NFHCs) by the Pechini method and their photocatalytic performance for the degradation of Rose Bengal (RB). Results indicate the presence of NiFe2O4 and alpha-Fe2O3 phases in NFHCs formed by octahedral and icosahedral particles with sizes from 20 to 1200 nm. The NFHC, with a Fe:Ni ratio of 70.5:29.5 wt%, achieved a superior RB degradation efficiency of 93 % after 120 min of solar irradiation. This performance was attributed to alpha-Fe2O3 acting as an electron mediator in the Z-scheme heterojunction mechanism.
引用
收藏
页数:5
相关论文
共 50 条
  • [1] Synthesis and photocatalytic performance of all-solid-state Z-scheme Ni3Fe/α-Fe2O3/NiFe2O4 heterojunction
    Xu, Qingxin
    Wang, Xiaoyi
    Ren, Benjing
    Sun, Yuqi
    Yu, Qiaoji
    Yang, Weiyang
    Meng, Jinhong
    OPTICAL MATERIALS, 2025, 159
  • [2] Photocatalytic performance of dual Z-scheme CoFe2O4/α-Fe2O3/Co3O4 ternary heterojunction composite synthesized by Pechini method
    Galvez-Barbosa, S.
    Gonzalez, Luis A.
    Bretado, Luis A.
    Vento-Lujano, Efrain
    Rosas, G.
    OPTICAL MATERIALS, 2024, 154
  • [3] Boosting the photocatalytic benzylamine oxidation and Rhodamine B degradation using Z-scheme heterojunction of NiFe2O4/rGO/Bi2WO6
    Xi, Hui
    Wang, Hui
    Liu, Dan
    Mu, Qiyun
    Xu, Xueqing
    Kang, Qiaoxiang
    Yang, Yaoxia
    Yang, Zhiwang
    Lei, Ziqiang
    JOURNAL OF ALLOYS AND COMPOUNDS, 2025, 1010
  • [4] Fe2O3/C3N4 composite nanotubular photocatalyst with Z-scheme heterojunction
    Liu, Jiaxin
    Liang, Haiou
    Li, Chunping
    Bai, Jie
    MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING, 2023, 162
  • [5] Z-scheme Fe2O3/g-C3N4 heterojunction with excellent photocatalytic property
    Zhang, Jian
    Jiang, Xinyu
    Gong, Mingkai
    Zheng, Yiqun
    JOURNAL OF PHOTONICS FOR ENERGY, 2020, 10 (02)
  • [6] A novel Z-scheme Bi4O5I2/NiFe2O4 heterojunction photocatalyst with reliable recyclability for Rhodamine B degradation
    Yang, Zhengxin
    Chen, Yan
    Xu, Longjun
    Liu, Chenglun
    Jiang, Zao
    ADVANCED POWDER TECHNOLOGY, 2021, 32 (12) : 4522 - 4532
  • [7] Construction of Br-Cu2O@NiFe-LDHs Z-scheme heterojunction and photocatalytic degradation of catechol
    Chen, Zhuying
    Huang, Zhiling
    Meng, Yue
    Xie, Bo
    Ni, Zheming
    Xia, Shengjie
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2024, 12 (05):
  • [8] Design of a α-Fe2O3/SiC heterojunction to improve photocatalytic performance through a Z-scheme electronic transfer
    Peng, Yuan
    Guo, Xiaotong
    Yang, Jingjing
    Xie, Taiping
    Wang, Jiankang
    Wang, Yajing
    Liu, Songli
    JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY, 2022, 43 (05) : 629 - 638
  • [9] Construction of facet orientation-supported Z-scheme heterojunction of BiVO4 (110)-Fe2O3 and its photocatalytic degradation of tetracycline
    Fu, Qiang
    Meng, Yue
    Yao, Yiyang
    Shen, Hui
    Xie, Bo
    Ni, Zheming
    Xia, Shengjie
    JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2023, 11 (05):
  • [10] Nanotextured Spikes of α-Fe2O3/NiFe2O4 Composite for Efficient Photoelectrochemical Oxidation of Water
    Hussain, Shabeeb
    Tayakoli, Mohammad Mandi
    Waleed, Aashir
    Virk, Umar Siddique
    Yang, Shihe
    Waseem, Amir
    Fan, Zhiyong
    Nadeem, Muhammad Arif
    LANGMUIR, 2018, 34 (12) : 3555 - 3564