[Cu(CN)en2]I - Copper amine propellers

被引：0
|
作者：
Institut für Anorganische Chemie, Universität Regensburg, Universitätsstraße 31, D-93040 Regensburg, Germany [1 ]
机构：
[1] Institut für Anorganische Chemie, Universität Regensburg, D-93040 Regensburg
来源：
Z. Naturforsch. Sect. B J. Chem. Sci. | 2006年 / 7卷 / 775-778期
关键词：
Amines; Copper (II) Complexes; Cyanide;
D O I：
10.1515/znb-2006-0701
中图分类号：
学科分类号：
摘要：
Light blue [Cu(CN)en2]I was prepared by reaction of copper iodide with ethylenediamine (en) and potassium cyanide in acetonitrile in air. It crystallizes in the space group C2 (No. 5) with a = 11.082(6), b = 7.155(2), c = 9.017(3) Å, β = 127.00(3)°, and Z = 2. The structure was refined from 1069 unique reflections and 90 parameters. The refinement converged to R1 = 0.018 and wR2 = 0.041 (all reflections). Copper has a trigonal bi-pyramidal environment formed by two en molecules and one CN- anion. The iodine anion shows no direct contact to the Cu2+ center. The propeller shaped complexes [Cu(CN)en2]+ are all oriented parallel in the crystal structure. [Cu(CN)en2]+ cations and I- anions form a zincblende related arrangement. © 2006 Verlag der Zeitschrift für Naturforschung.
引用
收藏
页码：775 / 778
页数：3
相关论文
共 50 条
  • [41] Unsymmetrical diarylethenes as molecular keypad locks with tunable photochromism and fluorescence via Cu2+ and CN- coordinations
    Zou, Qi
    Li, Xin
    Zhang, Junji
    Zhou, Ji
    Sun, Bingbing
    Tian, He
    CHEMICAL COMMUNICATIONS, 2012, 48 (15) : 2095 - 2097
  • [42] Coumarin based colorimetric and fluorescence on-off chemosensor for F-, CN- and Cu2+ ions
    Roy, Debashis
    Chakraborty, Arijit
    Ghosh, Rina
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2018, 191 : 69 - 78
  • [43] 1, 10-Phenanthroline based ESIPT sensor for cascade recognition of Cu2+ and CN- ions
    Kaur, Navneet
    Kaur, Gaganpreet
    Alreja, Priya
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2018, 353 : 138 - 142
  • [44] A new benzimidazole-based quinazoline derivative for highly selective sequential recognition of Cu2+ and CN-
    Tang, Lijun
    Wang, Nannan
    Zhang, Qiang
    Guo, Jiaojiao
    Nandhakumar, Raju
    TETRAHEDRON LETTERS, 2013, 54 (06) : 536 - 540
  • [45] The Thermal Behavior of Na[Au(CN)2] and the Gold(I) Dicyanaurate Complex Adsorbed on the Activated Carbon Surface
    Vorob'ev-Desyatovskii, N. V.
    Ibragimova, R. I.
    Kubyshkin, S. A.
    Yakovleva, O. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2010, 80 (11) : 2225 - 2230
  • [46] Syntheses, structures, and dynamic properties of M(CO)2(η3-C3H5)(en)(X) (M = Mo, W; X = Br, N3, CN) and [(en)(η3-C3H5)(CO)2M(μ-CN)M(CO)2 (η3-C3H5)(en)]Br (M = Mo, W)
    Liu, Fu-Chen
    Tsai, Tu-Chieh
    Lin, Yu-Liang
    Lee, Chen-Shiang
    Yang, Pei-Shan
    Wang, Ju-Chun
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (03) : 423 - 430
  • [47] Synthesis, Characterization, and Antibacterial Activity of [Cu2(L1)3(NCS)]•CH3CN and [Cu2Br2(L2)2(μ1,1-N3)2]
    Li, Jian-Nan
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2013, 43 (07) : 832 - 837
  • [48] A five-coordinate copper(II) perchlorate complex with tris(N-methylbenzimidazol-2-ylmethyl)amine and salicylate
    Wu, Hui-lu
    Huang, Xingcai
    Yuan, Jingkun
    Li, Ke
    Ding, Jian
    Yun, Ruirui
    Dong, Wenkui
    Fan, Xuyang
    JOURNAL OF COORDINATION CHEMISTRY, 2009, 62 (21) : 3446 - 3453
  • [49] Two new cyanide-bridged complexes, {[Cu(men)2][Ni(CN)4]} n and [Mn(bpy)2]4[Mo(CN)8]2•0.5MeOH•0.75H2O: Syntheses and crystal structures
    Chen, X.
    Yang, P.
    Ma, S. -L.
    Ren, S.
    Tang, M. -Y.
    Yang, Y.
    Guo, Z. -J.
    Liu, L. -Z.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2009, 50 (03) : 495 - 499
  • [50] Structural insights into the coordination and selective extraction of copper(II) by tertiary amine ligands derived from 2-aminomethylpyridine
    Yang, Jin-Peng
    Hu, Hui-Ping
    Cheng, Ze-Ying
    Qiu, Xue-Jing
    Wang, Cai-Xia
    POLYHEDRON, 2017, 128 : 76 - 84
12345