Nanoporous Metal-Organic Frameworks for Electroreduction of Nitrogen and Carbon Dioxide: A Review

被引：3

作者：

Kumar, Nikhil ^{[1
,3
]}

Gour, Kuldeep Singh ^{[2
,3
]}

Haider, Arsalan ^{[4
,5
]}

Kumar, Ravan ^{[6
]}

Park, Sungjin ^{[7
]}

机构：

[1] Natl Met Lab NML, CSIR, Adv Mat & Corros AMC Div, Funct Mat Grp, Jamshedpur 831007, Jharkhand, India

[2] Natl Met Lab NML, CSIR, Adv Mat & Corros AMC Div, Corros & Coating Grp, Jamshedpur 831007, Jharkhand, India

[3] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, Uttar Pradesh, India

[4] Korea Inst Sci & Technol KIST, Clean Energy Res Ctr, Seoul 02792, South Korea

[5] Korea Univ Sci & Technol UST, KIST Sch, Div Energy & Environm Technol, Republ Korea, Seoul 02792, South Korea

[6] Natl Inst Technol Sikkim, Dept Chem, Sikkim 737139, India

[7] Inha Univ, Dept Chem & Chem Engn, Michuholgu 22212, Incheon, South Korea

来源：

ACS APPLIED NANO MATERIALS | 2024年 / 7卷 / 24期

关键词：

MOFs; hybrid materials; NRR; ammoniaproduction; CO2RR; SINGLE-ATOM CATALYSTS; DOPED CARBON; ELECTROCHEMICAL SYNTHESIS; N-2; REDUCTION; N2; CO2; AMMONIA; OXYGEN; MOF; ELECTROCATALYSTS;

D O I：

10.1021/acsanm.4c05030

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The design and progress of smart hybrid materials are inspired by persistent challenges accompanied by the clean and green energy crisis and environmental remediation. However, the emergence of multifunctional nanomaterials has been captivating, and the real eagerness lies in decorating materials with flexible properties. The framework materials constituted with metal ions and organic ligands called metal-organic frameworks (MOFs) are recognized as promising candidates for electrocatalytic applications and gas adsorption. Still, their durability is challenged by low electrical conductivity, limited chemical stability, and intricate pores. Researchers have tried to develop MOF-assisted hybrid materials with rich surface chemistry due to their compositional versatility to improve pristine MOF stability. This review comprises the basic fundamentals and chemistry of MOFs, nitrogen reduction reaction (NRR), and electrochemical reduction of carbon dioxide (CO2RR), different types of MOF-based materials utilized for NRR and CO2RR, responsible factors, mechanistic pathways, and future viewpoints.

引用

页码：28074 / 28097

页数：24

共 147 条

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