Study on direct electrosynthetic conditions of 2-pyridinecarboxylic acid in plate and frame electrolytic cell

被引：0

作者：

Song, Cheng-Ying ^{[1
]}

Jin, Shao-Hua ^{[1
]}

Zhao, Jian-Hong ^{[1
]}

Wang, Liu-Cheng ^{[1
]}

机构：

[1] College of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, China

来源：

Xiandai Huagong/Modern Chemical Industry | 2007年 / 27卷 / 12期

关键词：

D O I：

暂无

中图分类号：

学科分类号：

摘要：

2-Pyridinecarboxylic acid (2-PCA) is prepared from 2-methylpyridine (2-MP) by the direct electrooxidation method in sulfuric acid solution with Ti/PbO2 as anode, and Pb as cathode in the plate and frame electrolytic cell, which is separated by a cation-exchange membrane. Under the preferable reaction conditions as:6% of the 2-MP mass fraction, 25% of H2SO4 mass fraction in anodic solution, charge amount, 0.5 times the theoretical value, 50 mA/cm2 of current density, and a temperature of 50°C, the average yield of 2-PCA can reach 94.19% ,and the average current efficiency,57.29%.

引用

页码：29 / 31

共 50 条

[31] COMPLEXATION EQUILIBRIA AND REDOX POTENTIALS OF THE MN(III)/MN(II) SYSTEM IN THE PRESENCE OF 2-PYRIDINECARBOXYLIC ACID IN AQUEOUS-SOLUTIONS
IGNACZAK, M
ANDRIJEWSKI, G
POLISH JOURNAL OF CHEMISTRY, 1995, 69 (05) : 716 - 722
[32] The in situ synthesis process and luminescence behavior of 2-pyridinecarboxylic acid europium complexes in the sol-gel derived host materials
Fan, XP
Wang, F
Lv, XH
Wang, MQ
Qiu, JB
Kawamoto, Y
MATERIALS CHEMISTRY AND PHYSICS, 2003, 82 (01) : 38 - 43
[33] Liquid phase oxidation of 2-methyl pyridine to 2-pyridinecarboxylic acid over cobalt-doped SBA-3
Li, Bin
Li, Lin
Sun, Lin
Xia, Fei
Wang, Siping
Wang, Jiaqiang
CATALYSIS COMMUNICATIONS, 2008, 9 (13) : 2287 - 2290
[34] RIFM fragrance ingredient safety assessment, 2-pyridinecarboxylic acid, ethyl ester, CAS Registry Number 2524-52-9
Api, A. M.
Belsito, D.
Botelho, D.
Bruze, M.
Burton, G. A., Jr.
Cancellieri, M. A.
Chon, H.
Dagli, M. L.
Dekant, W.
Deodhar, C.
Fryer, A. D.
Jones, L.
Joshi, K.
Kumar, M.
Lapczynski, A.
Lavelle, M.
Lee, I.
Liebler, D. C.
Moustakas, H.
Na, M.
Penning, T. M.
Ritacco, G.
Romine, J.
Sadekar, N.
Schultz, T. W.
Selechnik, D.
Siddiqi, F.
Sipes, I. G.
Sullivan, G.
Thakkar, Y.
Tokura, Y.
FOOD AND CHEMICAL TOXICOLOGY, 2023, 182
[35] SEPARATION OF METAL-IONS BY REVERSED-PHASE LIQUID-CHROMATOGRAPHY USING ON-COLUMN COMPLEXATION WITH 2-PYRIDINECARBOXYLIC ACID
NESTERENKO, PN
AMIROVA, GBZ
BOLSHOVA, TA
ANALYTICA CHIMICA ACTA, 1994, 285 (1-2) : 161 - 168
[36] OPTICALLY-ACTIVE TRANSITION-METAL COMPLEXES .58. REPRESENTATION AND EPIMERIZATION OF C5H5(CO)2MO DERIVATIVES OF 2-PYRIDINECARBOXYLIC AND 3-PYRIDINECARBOXYLIC ACID THIOAMIDES
BRUNNER, H
SPETTEL, G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 160 (01) : 149 - 158
[37] Di-μ-chloro-bis[(2-pyridinecarboxylato-N,O)-(2-pyridinecarboxylic acid-N,O)cadmium(II)] ethanol solvate
Odoko, M
Isomoto, N
Okabe, N
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : M371 - M372
[38] Extraction equilibrium and membrane transport of Copper(II) with new N-6-(t-Dodecylamido)-2-Pyridinecarboxylic acid in polymer inclusion membrane
Tasaki, Tsutomu
Oshima, Tatsuya
Baba, Yoshinari
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2007, 46 (17) : 5715 - 5722
[39] Crystal structure and electrochemical behavior of an unusual nitrosyl-Ru complex obtained by a reaction of Ru2(Me COO)4 Cl with 2-pyridinecarboxylic acid
Yukawa, Y
Igarashi, S
Horiike, H
Nagao, H
Howell, FS
Mukaida, M
CHEMISTRY LETTERS, 1999, (08) : 733 - 734
[40] MACROCYCLIC ENZYME MODEL SYSTEM - KINETIC ACTIVITY OF [20]PARACYCLOPHANE BEARING 1,4-DIHYDRONICOTINAMIDE AND 2-PYRIDINECARBOXYLIC ACID MOIETIES AS EFFECTED BY ZINC ION
MURAKAMI, Y
AOYAMA, Y
KIKUCHI, JI
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1982, 55 (09) : 2898 - 2901

← 1 2 3 4 5 →