Effects of humidity and solution age on growth of organosilane self-assembled monolayers

被引：0
|
作者：
Lee, Sunhyung [1 ]
Ishizaki, Takahiro [2 ]
Saito, Nagahiro [3 ,4 ]
Takai, Osamu [5 ]
机构：
[1] Faculty of Engineering, Shinshu University, Wakasato, Nagano 380-8553, Japan
[2] Materials Research Institute for Sustainable Development, National Institute of Advanced Industrial Science and Technology, 2266-98, Anagahora, Shimo-Shidami, Moriyama, Nagoya 463-8560, Japan
[3] Department of Materials, Physics and Energy Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603, Japan
[4] Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603, Japan
[5] EcoTopia Science Institute, Nagoya University, Furo-cho, Chikusa, Nagoya 464-8603, Japan
来源：
| 1600年 / Japan Society of Applied Physics卷 / 47期
关键词：
The effect of humidity on the self-organization and growth mechanism of octadecyltrichlorosilane (OTS) monolayers was investigated using an atomic force microscope (AFM); grazing incidence X-ray diffraction (GIXD); and Fourier transform IR spectroscopy (FT-IR). OTS self-assembled monolayers (SAMs) were prepared under humidity ranging from 5 to 80%. Under humidity ranging from 15 to 80%; OTS molecules produced domain structures early in the growth process that grew twodimensionally on SiO2 substrates. Also; the crystalline peaks of the obtained from the GIXD measurement indicated that OTSSAMs prepared under high humidity (15-80%) had grown in a crystalline state. Thus; self-organization occurred under these conditions. However; OTS-SAMs prepared under 5% humidity were in an amorphous structure. OTS-SAMs prepared at high humidity were denser than those prepared at low humidity. The domain size early in the growth process increased in proportion to the solution age. This shows that the reaction rate is governed by the hydrolysis of organosilane. On the other hand; solution age has no great influence on the density of the OTS-SAMs under conditions of more than 50% humidity. © 2008 The Japan Society of Applied Physics;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
相关论文
共 50 条
  • [1] Effects of Humidity and Solution Age on Growth of Organosilane Self-Assembled Monolayers
    Lee, Sunhyung
    Ishizaki, Takahiro
    Saito, Nagahiro
    Takai, Osamu
    JAPANESE JOURNAL OF APPLIED PHYSICS, 2008, 47 (08) : 6416 - 6421
  • [2] Effect of Reaction Temperature on Growth of Organosilane Self-Assembled Monolayers
    Lee, Sunhyung
    Ishizaki, Takahiro
    Saito, Nagahiro
    Takai, Osamu
    JAPANESE JOURNAL OF APPLIED PHYSICS, 2008, 47 (08) : 6442 - 6447
  • [3] Effect of reaction temperature on growth of organosilane self-assembled monolayers
    Lee, Sunhyung
    Ishizaki, Takahiro
    Saito, Nagahiro
    Takai, Osamu
    Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, 2008, 47 (8 PART 1): : 6442 - 6447
  • [4] Detecting and Removing Defects in Organosilane Self-Assembled Monolayers
    Hinckley, Adam P.
    Muscat, Anthony J.
    LANGMUIR, 2020, 36 (10) : 2563 - 2573
  • [5] Organosilane self-assembled monolayers formed at the vapour/solid interface
    Sugimura, H
    Hozumi, A
    Kameyama, T
    Takai, O
    SURFACE AND INTERFACE ANALYSIS, 2002, 34 (01) : 550 - 554
  • [6] Initial nucleation process of hydroxyapatite on organosilane self-assembled monolayers
    Ishikawa, M
    Zhu, PX
    Seo, WS
    Koumoto, K
    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2000, 108 (08) : 714 - 720
  • [7] Ion beam modification and patterning of organosilane self-assembled monolayers
    Ada, ET
    Hanley, L
    Etchin, S
    Melngailis, J
    Dressick, WJ
    Chen, MS
    Calvert, JM
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1995, 13 (06): : 2189 - 2196
  • [8] Organosilane self-assembled monolayers directly linked to the diamond surfaces
    Ohta, R
    Saito, N
    Inoue, Y
    Sugimura, H
    Takai, O
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2004, 22 (05): : 2005 - 2009
  • [9] Initial nucleation process of hydroxyapatite on organosilane self-assembled monolayers
    Ishikawa, Masahiko
    Zhu, Pei-Xin
    Seo, Won-Seon
    Koumoto, Kunihito
    Nippon Seramikkusu Kyokai Gakujutsu Ronbunshi/Journal of the Ceramic Society of Japan, 2000, 108 (1260): : 714 - 720
  • [10] Modification of PET surfaces with self-assembled monolayers of organosilane precursors
    Ozcam, Ali E.
    Efimenko, Kirill
    Jaye, Cherno
    Spontak, Richard J.
    Fischer, Daniel A.
    Genzer, Jan
    JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 2009, 172 (1-3) : 95 - 103
12345