Process development from laboratory to miniplant scale: Hydroformylation of 1-dodecene in thermomorphic solvent systems

被引：0
|
作者：
Verfahrensentwicklung vom Labor zur Miniplant: Hydroformylierung von 1-Dodecen in thermomorphen Lösungsmittelsystemen
机构：
[1] Technische Universität Dortmund, Lehrstuhl für Technische Chemie (Chemische Prozessentwicklung), 44227 Dortmund
来源：
Behr, A. (arno.behr@bci.tu-dortmund.de) | 1600年 / Wiley-VCH Verlag卷 / 86期
关键词：
Catalyst-recycling; Homogeneous catalysis; Hydroformylation; Miniplant; Rhodium; Thermomorphic multicomponent solvent systems;
D O I：
10.1002/cite.201300147
中图分类号：
学科分类号：
摘要：
The application of thermomorphic multicomponent solvent systems in chemical processing is able to significantly increase the effectivity and economy of homogenously catalyzed processes. The utilization of a strongly temperature-dependent miscibility gap of selected solvent combinations allows the performance of the reaction in a single phase and a subsequent catalyst separation through liquid-liquid two-phase technique. This elegant principle for catalysis is investigated using the rhodium catalyzed hydroformylation of 1-dodecene in a continuously driven miniplant. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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页码：449 / 457
页数：8
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