Stability of Strontium Zirconate Crucible for Induction Melting of Ti2Ni Alloys

被引:0
|
作者
Chen G. [1 ,2 ]
Yu F. [1 ]
Hou X. [1 ]
Yang Y. [1 ]
Xiao Y. [1 ]
Zhang Y. [1 ]
Zou X. [1 ]
Hou X. [1 ]
Lu X. [1 ,2 ]
Li C. [1 ,2 ]
机构
[1] State Key Laboratory of Advanced Special Steel & Shanghai Key Laboratory of Advanced Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, Shanghai
[2] Shanghai Special Casting Engineering Technology Research Center, Shanghai
[3] Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing
来源
Kuei Suan Jen Hsueh Pao/Journal of the Chinese Ceramic Society | 2021年 / 49卷 / 12期
关键词
Induction melting; Interaction; Refractory; Titanium alloys; Zirconate strontium;
D O I
10.14062/j.issn.0454-5648.20210284
中图分类号
学科分类号
摘要
A strontium zirconate oxide refractory was prepared by a solid-state reaction method at a mole ratio n(SrO): n(ZrO2) of 2:1 and 1400℃, and Ti2Ni alloys were melted in a crucible at 1750℃. The phase composition and microstructure of the refractory as well as the key features of Ti2Ni alloy melt interacted with the refractory crucible were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and optical microscopy (OM). The results reveal that the crucible refractory is consisted with the phases of Sr2ZrO4, Sr3Zr2O7 and SrO, respectively. The thermodynamically stable phase Sr2ZrO4 is unable to obtain separately due to the limitation of the reaction between SrCO3 and ZrO2, causing the residues of Sr3Zr2O7 and SrO. The thickness of interaction layer for the strontium zirconate oxide and barium zirconate crucible are 1250μm and 2120μm, respectively. The oxygen concentrations of the alloy after melting in strontium zirconate oxide and barium zirconate crucible are 0.332% and 0.566% (in mass fraction), respectively. It is indicated that the strontium zirconate oxide refractory exhibits a superior stability, compared to the barium zirconate refractory. © 2021, Editorial Department of Journal of the Chinese Ceramic Society. All right reserved.
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页码:2776 / 2782
页数:6
相关论文
共 20 条
  • [1] LUTJERING G, WILLIAMS J C., Titanium, pp. 1-2, (2007)
  • [2] KROLL W., The production of ductile titanium, Trans Electrochem Soc, 78, 1, pp. 35-47, (1940)
  • [3] DONG Hequan, GUO Ziming, MAO Xiemin, Et al., J Mater Rev(in Chinese), 22, pp. 68-73, (2008)
  • [4] BARBOSA J. J, SILVAL RIBERIRO C., Influence of crucible material on the level of contamination in TiAl using induction melting, Inter J Cast Met Res, 12, 5, pp. 293-301, (2000)
  • [5] TOSHIMITSU TETSUI, TOSHIHARU KOBAYASHI, TSUYOSHI UENO, Et al., Consideration of the influence of contamination from oxide crucibles on TiAl cast material, and the possibility of achieving low-purity TiAl precision cast turbine wheels, Intermetallics, 31, 5, pp. 274-281, (2012)
  • [6] KUANG J P, HARING R A, CAMPBELL J., Investigate into refactories as crucible and mould materials for melting and casting γ-TiAl alloys, Mater Sci Technol, 16, 9, pp. 1007-1016, (2000)
  • [7] KOSTOV A, FRIEDRICH B., Predicting thermodynamic stability of crucible oxides in molten titanium and titanium alloys, Comput Mater Sci, 38, 2, pp. 374-385, (2006)
  • [8] LIN K F, LIN C C., Interfacial reactions between Ti<sub>6</sub>Al<sub>4</sub>V alloy and zirconia mold during casting, J Mater Sci, 34, 23, pp. 5899-5906, (1999)
  • [9] GOMES F, BARBOSA J, RIBEIRO C S., Induction melting of γ-TiAl in CaO crucibles, Intermetallics, 16, 11, pp. 1292-1297, (2008)
  • [10] CUI R J, GAO M, ZHANG H., Interaction between TiAl alloys and yttria refractory material in casting process, Mater Process Technol, 210, 9, pp. 1190-1196, (2010)