Investigating metal-organic framework based on nickel (II) and benzene 1,3,5-tri carboxylic acid (H3BTC) as a new photocatalyst for degradation of 4-nitrophenol

被引：4
|
作者：
Arroussi A. [1 ]
Gaffour H. [1 ,2 ]
Mokhtari M. [1 ]
Boukli-Hacene L. [1 ]
机构：
[1] Laboratory of Inorganic Chemistry and Environment, Faculty of Sciences, University of Tlemcen, Tlemcen
[2] Departement of Chemistry, University of Adrar, Adrar
来源：
Boukli-Hacene, Leila (leila.bouklihacene@univ-tlemcen.dz) | 1600年 / Routledge卷 / 77期
关键词：
4-Nitrophenol (4-NP); degradation; MOF-Ni; organic pollutant; photocatalyst;
D O I：
10.1080/00207233.2019.1584479
中图分类号：
学科分类号：
摘要：
Metal-organic framework nickel (II) benzene tricarboxylate Ni3(BTC)2·12H2O (MOF-Ni) has been synthesised under solvothermal conditions and characterised by single crystal X-ray diffraction, Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA). The photocatalytic degradation of 4-nitrophenol (4-NP) using MOF-Ni under UV light irradiation was investigated and showed satisfactory results. A catalytic mechanism is proposed in terms of the HOMO-LUMO (highest occupied molecular orbital-lowest unoccupied molecular orbital) gap and the associated light-induced transition. The results showed that the studied MOF-based photocatalyst can be reused three to five times in the photocatalysis process and can degrade and mineralise 74% and 48% of 4-NP, respectively. © 2019, © 2019 Informa UK Limited, trading as Taylor & Francis Group.
引用
收藏
页码：137 / 151
页数：14
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