Coordinative flexibility in hydrotris(methimazolyl)borate divalent metal compounds

被引：23
作者：
Department of Chemistry, University of Akron, Akron, OH 44325-3601, United States [1 ]
机构：
[1] Department of Chemistry, University of Akron, Akron
来源：
Dalton Trans. | 2006年 / 8卷 / 1006-1008期
关键词：
Calcium - Chlorine compounds - Hydrogen bonds - Molecular structure - Negative ions - Synthesis (chemical) - Water;
D O I：
10.1039/b516558j
中图分类号：
学科分类号：
摘要：
The synthesis and structures of three divalent closed d shell metal complexes of the hydrotris(methimazolyl)borate divalent metal compound, were analyzed. The ligand acts as a non-coordinating anion for the metal ion Ca(II) and only engages in H-bonding with the metal bound water molecules. It was found that upon binding to Hg(II),the ligament forms a metal cluster compound, with an interstitial chloride in the center of a tetrahedral arrangement of metal ions. The results show that this diversity reflects the increased flexibility and the geometry of the ligand in contrast to tris(pyrazolyl)borate.
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页码：1006 / 1008
页数：2
相关论文
共 23 条
[11]  
Foreman M.R.St.-J., Hill A.F., Owen G.R., White A.J.P., Williams D.J., Organometallics, 22
[12]  
Graham L.A., Fout A.R., Kuehne K.R., White J.L., Mookherji B., Marks F.M., Yap G.P.A., Zakharov L.N., Rheingold A.L., Rabinovich D., Dalton Trans.
[13]  
Slavin P.A., Reglinski J., Spicer M.D., Kennedy A.R., J. Chem. Soc., Dalton Trans.
[14]  
Garner M., Lewinski K., Pattek-Janczyk A., Reglinski J., Sieklucka B., Spicer M.D., Szaleniec M., Dalton Trans.
[15]  
Dodds A., Jagoda M., Reglinski J., Spicer M.D., Polyhedron, 23
[16]  
Soares L.F., Silva R.M., Doriguetto A.C., Ellena J., Mascarenhas Y.P., Castellano E.E., J. Braz. Chem. Soc., 15
[17]  
Hill A.F., Owen G.R., White A.J.P., Williams D.J., Angew. Chem., Int. Ed., 18
[18]  
Santini C., Pettinari C., Lobbia G.G., Spagna R., Pellei M., Vallorani F., Inorg. Chim. Acta, 285
[19]  
Kimblin C., Churchill D.G., Bridgewater B.M., Girarad J.N., Quarless D.A., Parkin G., Polyhedron, 20
[20]  
Mihalcik D.J., White J.L., Tanski J.M., Zakharov L.N., Yap G.P.A., Incarvito C.D., Rheingold A.L., Rabinovich D., Dalton Trans.
123