Synthesis of ethyl tert-butyl ether with tert-butyl alcohol and ethanol on a H2SO4 activated bentonite

被引：0
|
作者：
Wu, Ding [1 ]
Chen, Chao [1 ]
Deng, Sheng-Jun [1 ]
Ding, Shun-Min [1 ]
Peng, Yan [1 ]
Zhang, Ning [1 ]
机构：
[1] Department of Chemistry, Nanchang University, Nanchang 330031, China
来源：
Journal of Molecular Catalysis | 2013年 / 27卷 / 05期
关键词：
Ethanol - Catalyst activity;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Bentonites have been treated by different concentrations H2SO4 solution, and x% H2SO4-BN (x=20, 25, 30, 35, 40) catalysts are obtained. XRD, BET, FT-IR, Py-IR and NH3-TPD are used to investigate the structure and properties of the bentonites, suggesting that the skeleton structure of the bentonites is not changed. Its surface area and pore volume are greatly improved in turn, and the week acid sites increase. Evaluation reaction of synthesis of ETBE from ethanol (EtOH) and tert-butyl alcohol (TBA) shows that 30% H2SO4-BN have the best catalytic activity, and the optimum experimental condition has been investigated.
引用
收藏
页码：413 / 419
相关论文
共 50 条
  • [31] Synthesis of Methyl tert-Butyl Ether from tert-Butyl Alcohol and Methanol Using Beta Zeolite Catalysts
    Jia-Yun Chen
    An-Nan Ko
    Reaction Kinetics and Catalysis Letters, 2000, 71 : 77 - 83
  • [32] Determination of adsorption and kinetic parameters for methyl tert-butyl ether synthesis from tert-butyl alcohol and methanol
    Zhang, ZY
    Hidajat, K
    Ray, AK
    JOURNAL OF CATALYSIS, 2001, 200 (02) : 209 - 221
  • [33] Sorption of methyl tert-butyl ether (MTBE) and tert-butyl alcohol (TBA) to synthetic resins
    Bi, EP
    Haderlein, SB
    Schmidt, TC
    WATER RESEARCH, 2005, 39 (17) : 4164 - 4176
  • [34] Roles of tert-butyl formate, tert-butyl alcohol and acetone in the regulation of methyl tert-butyl ether degradation by Mycobacterium austroafricanum IFP 2012
    Francois, A
    Garnier, L
    Mathis, H
    Fayolle, F
    Monot, F
    APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2003, 62 (2-3) : 256 - 262
  • [35] Roles of tert-butyl formate, tert-butyl alcohol and acetone in the regulation of methyl tert-butyl ether degradation by Mycobacterium austroafricanum IFP 2012
    A. François
    L. Garnier
    H. Mathis
    F. Fayolle
    F. Monot
    Applied Microbiology and Biotechnology, 2003, 62 : 256 - 262
  • [36] THE ATMOSPHERIC CHEMISTRY OF OXYGENATED FUEL ADDITIVES - TERT-BUTYL ALCOHOL, DIMETHYL ETHER, AND METHYL TERT-BUTYL ETHER
    JAPAR, SM
    WALLINGTON, TJ
    RICHERT, JFO
    BALL, JC
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1990, 22 (12) : 1257 - 1269
  • [37] KINETICS OF LIQUID-PHASE SYNTHESIS OF ETHYL TERT-BUTYL ETHER FROM TERT-BUTYL ALCOHOL AND ETHANOL CATALYZED BY ION-EXCHANGE RESIN AND HETEROPOLY ACID
    YIN, XD
    YANG, BL
    GOTO, S
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1995, 27 (11) : 1065 - 1074
  • [38] Synthesis of ethyl tert-butyl ether in a NaA membrane reactor
    Cao Y.
    Li Y.-X.
    Ma X.-H.
    Xu Z.-L.
    Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities, 2021, 35 (04): : 649 - 656
  • [39] Synthesis and characterization of a gasoline oxygenate, ethyl tert-butyl ether
    Donahue, CJ
    D'Amico, T
    Exline, JA
    JOURNAL OF CHEMICAL EDUCATION, 2002, 79 (06) : 724 - 726
  • [40] Compressed liquid densities of methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), and diisopropyl ether (DIPE)
    Ihmels, EC
    Gmehling, J
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2002, 47 (05): : 1307 - 1313
12345