Synthesis, thermostability, and photophysical properties of Nd(III) complexes with carboxylic acids

被引：0

作者：

Hu, Li ^{[1
,2
]}

Yin, Qiang ^{[2
]}

Zhang, Jinli ^{[2
]}

Du, Kai ^{[2
]}

机构：

[1] School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China

[2] Research Center of Laser Fusion, CAEP, Mianyang 621900, China

来源：

Qiangjiguang Yu Lizishu/High Power Laser and Particle Beams | 2014年 / 26卷 / 03期

关键词：

Carboxylic acids - Rare earths - Infrared devices - Neodymium compounds - Fluorescence - Synthesis (chemical) - Stability;

D O I：

10.3788/HPLPB201426.032005

中图分类号：

学科分类号：

摘要：

In order to observe the amplified emission of rare earth complexes, three Nd(III) complexes were successfully synthesized using three carboxylic acids (H3BTC, H6MTA and H6CCA) as ligands and characterized by elemental analysis, ICP and FTIR. Thermostability was studied by TGA spectra. Fluorescence properties were investigated by fluorescence spectra. The fluorescence spectra of the three complexes were composed of typical Nd(III) ions in near infrared emissions, assigned to transitions of 4F3/2→4I9/2, 4F3/2→4I11/2 and 4F3/2→4I13/2. The results indicated that prepared Nd(III) complexes showed considerable thermostability and well fluorescence properties, which would make them promising materials for laser active medium.

引用

共 50 条

[21] Cluster rhenium(III) complexes with adamantanecarboxylic acids: Synthesis and properties
Golichenko, AA
Shtemenko, AV
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2006, 32 (04) : 242 - 249
[22] Cluster rhenium(III) complexes with adamantanecarboxylic acids: Synthesis and properties
A. A. Golichenko
A. V. Shtemenko
Russian Journal of Coordination Chemistry, 2006, 32 : 242 - 249
[23] Synthesis and Spectral Properties of Terbium(III) and Gadolinium(III) Complexes with Hydroxybenzoic Acids
Nazarenko, M. A.
Oflidi, A. I.
Panyushkin, V. T.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2019, 89 (03) : 434 - 439
[24] Synthesis and Spectral Properties of Terbium(III) and Gadolinium(III) Complexes with Hydroxybenzoic Acids
M. A. Nazarenko
A. I. Oflidi
V. T. Panyushkin
Russian Journal of General Chemistry, 2019, 89 : 434 - 439
[25] In-situ synthesis and fluorescence properties of rare earth Eu(III) and Tb(III) complexes with aromatic carboxylic acids in silica gel glasses
Qian, Guodong
Wang, Minquan
Kuei Suan Jen Hsueh Pao/ Journal of the Chinese Ceramic Society, 26 (03): : 331 - 337
[26] Photophysical properties of praseodymium complexes with aromatic carboxylic acids: Double light conversion both in ultraviolet and visible region
Yan, Bing
Wang, Weijing
Song, Yishan
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2007, 66 (4-5) : 1115 - 1121
[27] The photophysical properties of binary and ternary complexes of rare earths with conjugated carboxylic acids and 1,10-phenanthroline
Zhang, HJ
Yan, B
Wang, SB
Ni, JZ
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1997, 109 (03) : 223 - 228
[28] The photophysical properties of binary and ternary complexes of rare earths with conjugated carboxylic acids and 1,10-phenanthroline
J Photochem Photobiol A Chem, 3 (223):
[29] Effect of substituents on the photoluminescence performance of Ir(III) complexes: Synthesis, electrochemistry and photophysical properties
Jayabharathi, J.
Thanikachalam, V.
Saravanan, K.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2009, 208 (01) : 13 - 20
[30] Synthesis and photophysical properties of bis-cyclometalated iridium (III) dipyrrin complexes.
Tamayo, AB
Ly, J
Ma, BW
Djurovich, PI
Thompson, ME
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U1106 - U1107

← 1 2 3 4 5 →