Synthesis, thermostability, and photophysical properties of Nd(III) complexes with carboxylic acids

被引：0
作者：
Hu, Li [1 ,2 ]
Yin, Qiang [2 ]
Zhang, Jinli [2 ]
Du, Kai [2 ]
机构：
[1] School of Material Science and Engineering, Southwest University of Science and Technology
[2] Research Center of Laser Fusion, CAEP
来源：
Qiangjiguang Yu Lizishu/High Power Laser and Particle Beams | 2014年 / 26卷 / 03期
关键词：
Carboxylic acid; Fluorescence property; Inertial confinement fusion; Nd(III) complexes; Thermostability;
D O I：
10.3788/HPLPB201426.032005
中图分类号：
学科分类号：
摘要：
In order to observe the amplified emission of rare earth complexes, three Nd(III) complexes were successfully synthesized using three carboxylic acids (H3BTC, H6MTA and H6CCA) as ligands and characterized by elemental analysis, ICP and FTIR. Thermostability was studied by TGA spectra. Fluorescence properties were investigated by fluorescence spectra. The fluorescence spectra of the three complexes were composed of typical Nd(III) ions in near infrared emissions, assigned to transitions of 4F3/2→4I9/2, 4F3/2→4I11/2 and 4F3/2→4I13/2. The results indicated that prepared Nd(III) complexes showed considerable thermostability and well fluorescence properties, which would make them promising materials for laser active medium.
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  • [1] Liu K., Du K., Chen J., Et al., Fabrication of high quality ordered porous anodic aluminum oxide templates, High Power Laser and Particle Beams, 22, 7, pp. 1531-1534, (2010)
  • [2] Zhang Z., Huang Y., Liu Y., Et al., Fabrication of gas-filled targets without gas source, High Power Laser and Particle Beams, 21, 1, pp. 79-82, (2009)
  • [3] Li Y., Gao S., Wu D., Et al., Phase transition cooling of 3 kW pulsed diode laser stack, High Power Laser and Particle Beams, 24, 1, pp. 43-45, (2012)
  • [4] Ye Y., Fan D., Progress of rare-earth-doped liquid laser, Laser and Optoelectronics Progress, 44, 1, pp. 45-50, (2007)
  • [5] Tang G., Xiao Z., Zuo C., Et al., Progress in research on Nd<sup>3+</sup> ion-doped laser materials, Materials Review, 23, 6, pp. 40-44, (2009)
  • [6] Zhang X., Spectroscopic studies on the luminescence properties of ternary europium complexes with different ligands, Jouranal of Luminescence, 130, 6, pp. 1060-1066, (2010)
  • [7] Gu Y., Yan B., Qiao X., Novel light-conversion hybrids of SBA-16 functionalized with rare earth (Eu<sup>3+</sup>, Nd<sup>3+</sup>, Yb<sup>3+</sup>) complexes of modified 2-methyl-9-hydroxyphenalenone and 1, 10-phenanthroline, Journal of Solid State Chemistry, 199, pp. 116-122, (2013)
  • [8] Xu C., Synthesis, structure and properties of rare earth carboxylic acid complexes, (2005)
  • [9] Bunzli J.C.G., Piguet C., Taking advantage of luminescent lanthanide ions, Chemical Society Review, 34, 12, pp. 1048-1077, (2005)
  • [10] Wasterlund F., Nordell F., Blechinger J., Complex DNA binding kinetics resolved by combined circular dichroism and luminescence analysis, Journal of Physical Chemistry B, 112, 21, pp. 6688-6694, (2008)
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