Liquid Phase Peroxide Oxidation of Phenol in the Presence of Catalysts Based on Mixed Oxides of Transition Metals and Cellulose

被引：0
作者：
Perebeinos, A. A. [1 ]
Mishchenko, T. I. [2 ]
Gurovskii, V. V. [1 ]
Medvedeva, T. B. [2 ]
Yatsenko, D. A. [2 ]
Gromov, N. V. [1 ,2 ]
机构：
[1] Novosibirsk State Tech Univ, Novosibirsk 630073, Russia
[2] Russian Acad Sci, Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2024年 / 97卷 / 05期
关键词：
wastewater; phenol; liquid-phase peroxide oxidation; ferrites; DEGRADATION; DECOMPOSITION;
D O I：
10.1134/S1070427224050021
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
AbstractThe work is devoted to the study of the process of water purification from phenol, which was oxidized in the process of liquid-phase peroxide oxidation in the presence of catalysts of composite materials based on MeFe2O4 (Me = Mn, Co, Mg, Cu) and cellulose. The textural and acidic properties of the catalysts were studied. It was shown that the main phase of the catalysts is MeFe2O4, acidity of aqueous suspensions of catalysts are neutral and slightly alkaline. Among the tested catalysts, the CuFe2O4/CMC (microcrystalline cellulose) sample had the greatest efficiency, in the presence of which the phenol conversion was achieved 100% for 20 min of reaction time. Copper and manganese had the greatest effectiveness as Me in the MeFe2O4/CMC system.
引用
收藏
页码：493 / 506
页数：14
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