Photopolymerization behaviors of novel two-photon absorption initiators and fabrication of microdevices

被引：0

作者：

Guo, Fuquan ^{[1
,2
]}

Hu, Zhiyuan ^{[1
]}

Fu, Xinjian ^{[1
]}

Zhang, Qijing ^{[2
]}

Huang, Wenhao ^{[3
]}

Xia, Andong ^{[3
]}

机构：

[1] Department of Materials Science and Engineering, Luoyang Institute of Science and Technology, Luoyang, Henan 471023, China

[2] Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, China

[3] Department of Precision Machinery and Precision Instrument, University of Science and Technology of China, Hefei, Anhui 230026, China

来源：

Zhongguo Jiguang/Chinese Journal of Lasers | 2009年 / 36卷 / 06期

关键词：

Nonlinear optics - Photons - Pumping (laser) - Luminescence of organic solids - Two photon processes;

D O I：

10.3788/CJL20093606.1528

中图分类号：

学科分类号：

摘要：

Three novel stilbene derivatives (named as BPSBP, BESBP and BCSBP respectively) with D-π-D molecular motif, used as two-photon absorption (TPA) initiators, are designed and synthesized aimed at the excitation source of 800 nm. TPA induced photopolymerization behaviors are studied with the pumping of a femtosecond laser. Effects of the concentrations of TPA initiators on initiation thresholds and effects of the concentrations of TPA initiators, the polymerized energy and the exposure time on the resolution in polymerization are discussed in detail. 3D periodic microstructure with submicrometer resolution is fabricated and characterized by scanning elletron microscope (SEM) under optimized conditions using BPSBP as TPA initiators with the concentration of 32 μmol/g and polymerized energy of 9105 mJ/cm2.

引用

页码：1528 / 1534

共 50 条

[21] Fabrication of Novel Biocompatible Surfaces by Two-Photon Absorption Technique Using Femtosecond Laser
Tanaka, Masaru
Sato, Hirokazu
Sasaya, Yugo
Horinouchi, Suguru
Hotta, Jun-ichi
Matsuo, Yasutaka
Ijiro, Kuniharu
Sasaki, Keiji
Shimomura, Masatsugu
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2009, 505 : 457 - 468
[22] Two-Photon Absorption and the Design of Two-Photon Dyes
Pawlicki, Milosz
Collins, Hazel A.
Denning, Robert G.
Anderson, Harry L.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (18) : 3244 - 3266
[23] Synthesis and nonlinear optical properties of several new two-photon photopolymerization initiators about dibenzothiophene derivatives
Zhang, Xian
Sun, Yuming
Yu, Xiaoqiang
Zhang, Baoqin
Huang, Baibiao
Jiang, Minhua
SYNTHETIC METALS, 2009, 159 (23-24) : 2491 - 2496
[24] Influence of two-photon absorption on the dynamic behaviors of microring resonators
Li, Qiliang
Chen, Haowen
Xu, Jie
Hu, Miao
Zeng, Ran
Zhou, Xuefang
Li, Shuqin
APPLIED OPTICS, 2017, 56 (10) : 2580 - 2588
[25] Two-photon absorption
Pérez-Arjona, I
de Valcárcel, GJ
Roldán, E
REVISTA MEXICANA DE FISICA, 2003, 49 (01) : 92 - 101
[26] SYNTHESIS OF A SERIES OF NOVEL ORGANIC COMPOUNDS WITH TWO-PHOTON ABSORPTION AND TWO-PHOTON PUMPED LASING
Xiao Mei WANG
Chinese Chemical Letters, 2001, (01) : 27 - 30
[27] Synthesis of a series of novel organic compounds with two-photon absorption and two-photon pumped lasing
Wang, XM
Fang, Q
Wang, C
Zhou, GY
Ren, Y
Jiang, MH
CHINESE CHEMICAL LETTERS, 2001, 12 (01) : 27 - 30
[28] Water soluble initiators for two-photon polymerization
Li, Z.
Qin, X.
Ovsianikov, A.
Torgersen, T.
Ajami, A.
Husinsky, H.
Muehleder, S.
Holnthoner, W.
Stampfl, J.
Liska, R.
JOURNAL OF TISSUE ENGINEERING AND REGENERATIVE MEDICINE, 2012, 6 : 369 - 369
[29] Two-photon absorption strength: A new tool for the quantification of two-photon absorption
Fortrie, Remy
Chermette, Henry
JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (20):
[30] Two-photon photopolymerization with multiple laser beams
Jakl, Petr
Skalicky, Jiri
Jezek, Jan
Sery, Mojmir
Novotny, Dusan
Zemanek, Pavel
20TH SLOVAK-CZECH-POLISH OPTICAL CONFERENCE ON WAVE AND QUANTUM ASPECTS OF CONTEMPORARY OPTICS, 2016, 10142

← 1 2 3 4 5 →