A novel and faster route for the synthesis of polyether-polycarbonate from carbon dioxide and epoxide through microwave irradiation

被引：0
作者：
Department of Chemical Engineering, Pusan National University, Busan, 609-735, Korea, Republic of [1 ]
机构：
[1] Department of Chemical Engineering, Pusan National University, Busan
来源：
Res Chem Intermed | 2008年 / 8-9卷 / 835-844期
基金：
新加坡国家研究基金会;
关键词：
Carbon dioxide; Co-polymerization; Microwave; Polyether-polycarbonate;
D O I：
10.1163/156856708786189285
中图分类号：
学科分类号：
摘要：
The purpose of this study was to investigate the utilization of CO 2 in order to obtain polyether-polycarbonate by the co-polymerization of epoxide with CO2 using microwave irradiation. Double metal cyanide containing Zn with Co, Fe(II), Fe(III) and Ni has been utilized as a catalyst for the co-polymerization reaction. The effect of microwave power, catalyst amount and types of catalysts has been studied. The microwaves were found to be successful in the synthesis of polyether-polycarbonate in a shorter reaction time with higher turnover numbers than those in conventional methods. © 2008 VSP.
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页码：835 / 844
页数：9
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