Improving thermal conductivity of Mg-Si-Zn-Cu alloy through minimizing electron scattering at phase interface

被引:13
作者
Chen, Lu [1 ]
Lu, Shulin [1 ]
Li, Jianyu [1 ]
Guo, Wei [1 ]
Wu, Shusen [1 ]
机构
[1] Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, State Key Lab Mat Proc & Die & Mould Technol, Wuhan 430074, Peoples R China
基金
中国国家自然科学基金;
关键词
Thermal conductivity; Ce modification; Mg2Si; Heat treatment; MAGNESIUM ALLOYS; HEAT-TREATMENT; MICROSTRUCTURE; BINARY; TEMPERATURE; AL;
D O I
10.1016/j.jma.2023.03.012
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The primary cause of the decrease in thermal conductivity of conventional thermal conductive magnesium alloys is electron scattering brought on by solute atoms. However, the impact of phase interface on thermal conductivity of magnesium alloys is usually disregarded. This study has developed a Mg-Si-Zn-Cu alloy with high thermal conductivity that is distinguished by having a very low solute atom content and a significant number of phase interfaces. The thermal conductivity of the Mg-1.38Si-0.5Zn-0.5Cu alloy raises from its untreated value of 133.2 W/(m <middle dot>K) to 142.2 W/(m <middle dot>K), which is 91% of the thermal conductivity of pure Mg. This is accomplished by subjecting the alloy to both 0.8wt% Ce modification and T6 heat treatment. The morphology of eutectic Mg2 Si phase is changed by Ce modification and heat treatment, and as a result, the scattering of electrons at the Mg2 Si/Mg interface is reduced, resulting in increase of the alloy's thermal conductivity. (c) 2023 Chongqing University. Publishing services provided by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ ) Peer review under responsibility of Chongqing University
引用
收藏
页码:3717 / 3728
页数:12
相关论文
共 33 条
[11]   Microstructure and thermal conductivity of Mg-2Zn-Zr alloy [J].
Li, Bingcheng ;
Hou, Legan ;
Wu, Ruizhi ;
Zhang, Jinghuai ;
Li, Xinlin ;
Zhang, Milin ;
Dong, Anping ;
Sun, Baode .
JOURNAL OF ALLOYS AND COMPOUNDS, 2017, 722 :772-777
[12]   Dramatically reduced lattice thermal conductivity of Mg2Si thermoelectric material from nanotwinning [J].
Li, Guodong ;
He, Jiangang ;
An, Qi ;
Morozov, Sergey I. ;
Hao, Shigiang ;
Zhai, Pengcheng ;
Zhang, Qingjie ;
Goddard, William A., III ;
Snyder, G. Jeffrey .
ACTA MATERIALIA, 2019, 169 :9-14
[13]   Effect of nano rare earth phase on microstructure and properties in rapidly solidifying Mg-Si-RE alloys [J].
Li, Yaohui ;
Li, Ke ;
Dai, Jia ;
Han, Wenduo ;
Yin, Wenlai ;
Li, Yifan ;
Hu, Zhi .
MATERIALS TODAY COMMUNICATIONS, 2021, 27 (27)
[14]   Microstructure and compressive properties of solution heat-treated magnesium-Mg2Si in-situ composite foams after complex modification [J].
Liu, J. A. ;
Song, D. ;
Zhang, L. R. ;
Yang, X. Z. ;
Zhu, X. Y. ;
Sun, W. B. ;
Chen, F. Y. .
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2021, 15 :3673-3682
[15]   A Quantitative Study on the Interaction Between Silicon Content and Heat Treatment on Thermal Conductivity of Al-Si Binary Alloys [J].
Luo, Gan ;
Zhou, Xiong ;
Li, Chengbo ;
Du, Jun ;
Huang, Zhenghua .
INTERNATIONAL JOURNAL OF METALCASTING, 2022, 16 (03) :1585-1594
[16]   Effect of holding temperature on microstructure of an AS91 alloy during semisolid isothermal heat treatment [J].
Ma, G. R. ;
Li, X. L. ;
Xiao, L. ;
Li, Q. F. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 496 (1-2) :577-581
[17]   Improvement of mechanical properties of in situ Mg-Si composites via Cu addition and hot working [J].
Maleki, Milad ;
Mirzadeh, Hamed ;
Emamy, Massoud .
JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 905
[18]  
Mills K.C., 2002, Recommended values of thermophysical properties for selected commercial alloys, DOI DOI 10.1533/9781845690144
[19]   Reconsideration of the concept of critical nucleus and the Gibbs-Thomson equation [J].
Nishioka, K ;
Maksimov, IL .
JOURNAL OF CRYSTAL GROWTH, 1996, 163 (1-2) :1-7
[20]   Thermal and electrical conductivity of binary magnesium alloys [J].
Pan, Hucheng ;
Pan, Fusheng ;
Yang, Rumin ;
Peng, Jian ;
Zhao, Chaoyong ;
She, Jia ;
Gao, Zhengyuan ;
Tang, Aitao .
JOURNAL OF MATERIALS SCIENCE, 2014, 49 (08) :3107-3124