Progress in defect modulation of g-C3N4 based materials and its photocatalytic property

被引:0
作者
Lu, Yu [1 ,2 ]
Liu, Chengbao [1 ,2 ,3 ]
Zheng, Leizhi [1 ,2 ,3 ]
Chen, Feng [1 ,2 ,3 ]
Qiu, Yongbin [4 ]
Meng, Xianrong [5 ]
Chen, Zhigang [1 ,2 ,3 ]
机构
[1] Jiangsu Key Laboratory for Environment Functional Materials, Suzhou University of Science and Technology, Suzhou
[2] School of Materials Science and Engineering, Suzhou University of Science and Technology, Suzhou
[3] Jiangsu Collaborative Innovation Center of Technology and Material for Water Treatment, Suzhou University of Science and Technology, Suzhou
[4] Jiangsu Province Ceramics Research Institute CO., LTD., Yixing
[5] Suzhou Institute of Environmental Science, Suzhou
来源
Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica | 2024年 / 41卷 / 11期
关键词
defect modulation; environmental pollution; graphitic carbon nitride; modulation strategy; photocatalysis; semiconductor;
D O I
10.13801/j.cnki.fhclxb.20240320.003
中图分类号
学科分类号
摘要
Semiconductor photocatalytic materials have become a key factor of photocatalytic technologies to solve environmental pollution and energy crisis. Among them, graphitic phase carbon nitride (g-C3N4) has shown great potential for application as an emerging highly efficient catalytic material. However, the unmodified g-C3N4 has disadvantages such as limited visible light response range, less reactive sites and high photogenerated carrier complexation rate, which severely limit its practical applications. Thus, researchers have adopted various strategies, such as designing and developing heterogeneous structures, defect engineering and morphological modulation to solve the problems mentioned above. Among them, defect modulation has attracted much attention because it can effectively modulate the electronic band structure of photocatalytic materials, delay carrier recombination and increase the surface reactive sites. This paper describes the types of defect modulations, defect modulation strategies, and finally summarizes the development and application of g-C3N4 based photocatalytic materials and gives an outlook. © 2024 Beijing University of Aeronautics and Astronautics (BUAA). All rights reserved.
引用
收藏
页码:5737 / 5753
页数:16
相关论文
共 85 条
  • [1] ONG W J, TAN L L, NG Y H, Et al., Graphitic carbon nitride (g-C<sub>3</sub>N<sub>4</sub>)-based photocatalysts for artificial photosynthesis and environmental remediation: Are we a step closer to achieving sustainability?, Chemical Reviews, 116, 12, pp. 7159-7329, (2016)
  • [2] MA Y, WANG X, JIA Y, Et al., Titanium dioxide-based nanomaterials for photocatalytic fuel generations, Chemical Reviews, 114, 19, pp. 9987-10043, (2014)
  • [3] CHEN X, SHEN S, GUO L, Et al., Semiconductor-based photocatalytic hydrogen generation, Chemical Reviews, 110, 11, pp. 6503-6570, (2010)
  • [4] YAN S C, LI Z S, ZOU Z G., Photodegradation performance of g-C<sub>3</sub>N<sub>4</sub> fabricated by directly heating melamine, Langmuir: The ACS Journal of Surfaces and Colloids, 25, 17, pp. 10397-10401, (2009)
  • [5] ZHANG X, XIE X, WANG H, Et al., Enhanced photoresponsive ultrathin graphitic-phase C<sub>3</sub>N<sub>4</sub> nanosheets for bioimaging, Journal of the American Chemical Society, 135, 1, pp. 18-21, (2013)
  • [6] DONG F, ZHAO Z, XIONG T, Et al., In situ construction of g-C<sub>3</sub>N<sub>4</sub>/g-C<sub>3</sub>N<sub>4</sub> metal-free heterojunction for enhanced visible-light photocatalysis, ACS Applied Materials & Interfaces, 5, 21, pp. 11392-11401, (2013)
  • [7] XU Yang, LIU Chengbao, ZHENG Leizhi, Et al., Research progress of high crystallinity g-C<sub>3</sub>N<sub>4</sub> in photocatalysis, Materials Reports, 3, 1, pp. 1-20, (2024)
  • [8] WANG Y, CHEN J, LIU L, Et al., Novel metal doped carbon quantum dots/CdS composites for efficient photocatalytic hydrogen evolution, Nanoscale, 11, 4, pp. 1618-1625, (2019)
  • [9] TAY Q, WANG X, ZHAO X, Et al., Enhanced visible light hydrogen production via a multiple heterojunction structure with defect-engineered g-C<sub>3</sub>N<sub>4</sub> and two-phase anatase/brookite TiO<sub>2</sub>, Journal of Catalysis, 342, pp. 55-62, (2016)
  • [10] FU J, MO Z, CHEN H, Et al., Three coordinate nitrogen (N<sub>3c</sub>) vacancies from in-situ hydrogen bond breaking over polymeric carbon nitride for efficient photocatalysis, Journal of Environmental Chemical Engineering, 11, 2, (2023)