Recent research and prospect of liquid organic hydrogen carries technology

被引：0
作者：
Liu R. [1 ]
Tang H. [1 ]
He F. [2 ]
Luo F. [1 ]
Wang J. [2 ]
Yang N. [2 ]
Li H. [2 ]
Zhang R. [1 ,2 ,3 ]
机构：
[1] Foshan Xianhu Laboratory, Advanced Energy Science and Technology Guangdong Laboratory, Guangdong, Foshan
[2] Guangdong Hanrui Hydrogen Energy Technology Company Limited, Guangdong, Foshan
[3] Guangdong Hydrogen Energy Institute of WHUT, Guangdong, Foshan
来源：
Huagong Jinzhan/Chemical Industry and Engineering Progress | 2024年 / 43卷 / 04期
关键词：
aromatic hydrocarbons; aza-aromatic hydrocarbons; catalyst; dehydrogenation; hydrogen; hydrogen storage material; hydrogenation; liquid organic hydrogen carriers;
D O I：
10.16085/j.issn.1000-6613.2023-0515
中图分类号：
学科分类号：
摘要：
As the vision of building a green hydrogen society, the demand for hydrogen energy will grow massively on a large scale as well, but the storage and transportation will also be the bottleneck that restricts the scale of the industrial development. Liquid organic hydrogen carries (LOHCs) have advantages over conventional high-pressure hydrogen storage methods in terms of low cost and safety for the large-scale storage and long-distance transportation of hydrogen energy. However, this technology is still at the early stage of development, and the related reports are limited. This paper reviews the main liquid organic hydrogen materials, aromatic such as aromatic hydrocarbons and aza-aromatic hydrocarbons, and analyses their hydrogen storage properties, advantages, problems and development status. Furthermore, various metal catalysts involved in hydrogenation and dehydrogenation processes are described. Finally, based on the current research, the prospects for liquid organic hydrogen storage technology are presented and the feasibility of liquid organic hydrogen storage technology in various fields and its high economic values are pointed out. However, for large-scale application, it’s necessary to select the optimal liquid organic hydrogen materials, develop new catalysts with high selectivity, high catalytic activity and low cost, and further optimize hydrogenation and dehydrogenation technologies. © 2024 Chemical Industry Press Co., Ltd.. All rights reserved.
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页码：1731 / 1741
页数：10
相关论文
共 58 条
  • [1] YASUSHI Sekine, TAKUMA Higo, Recent trends on the dehydrogenation catalysis of liquid organic hydrogen carrier (LOHC): A review, Topics in Catalysis, 64, 7, pp. 470-480, (2021)
  • [2] ZHOU Yiming, QI Suitao, ZHOU Yuliang, Et al., Research progress in the hydrogenation and dehydrogenation technology of polycyclic aromatic hydrocarbon liquid organic hydrogen carriers, Chemical Industry and Engineering Progress, 42, 2, pp. 1000-1007, (2023)
  • [3] ZHANG Yuanyuan, ZHAO Jing, LU Xilan, Et al., Progress in liquid organic hydrogen storage materials, Chemical Industry and Engineering Progress, 35, 9, pp. 2869-2874, (2016)
  • [4] MODISHA Phillimon M, OUMA Cecil N M, GARIDZIRAI Rudaviro, Et al., The prospect of hydrogen storage using liquid organic hydrogen carriers, Energy & Fuels, 33, 4, pp. 2778-2796, (2019)
  • [5] SONG Pengfei, HOU Jianguo, WANG Xiulin, Research progress on methylcyclohexane-toluene liquid organic hydrogen storage technology, Natural Gas Chemical Industry, 46, pp. 18-23, (2021)
  • [6] WANG Meng'en, TIAN Yafei, ZHANG Zhifang, Et al., Thermodynamic calculation of dehydrogenation of cyclohexane, methyl cyclohexane and ethyl cyclohexane, Petrochemical Technology & Application, 40, 4, pp. 238-242, (2022)
  • [7] BRUCKNER Nicole, OBESSER Katharina, BOSMANN Andreas, Et al., Evaluation of industrially applied heat-transfer fluids as liquid organic hydrogen carrier systems, ChemSusChem, 7, 1, pp. 229-235, (2014)
  • [8] BOLLMANN Jonas, SCHMIDT Nikolas, BECK Dominik, Et al., A path to a dynamic hydrogen storage system using a liquid organic hydrogen carrier (LOHC): Burner-based direct heating of the dehydrogenation unit, International Journal of Hydrogen Energy, 48, 3, pp. 1011-1023, (2023)
  • [9] DURR S, ZILM S, GEIssELBRECHT M, Et al., Experimental determination of the hydrogenation/dehydrogenation-Equilibrium of the LOHC system H0/H18-dibenzyltoluene, International Journal of Hydrogen Energy, 46, 64, pp. 32583-32594, (2021)
  • [10] MA Jialing, YIN Lifei, LING Lixia, Et al., The formation of high energy density fuel via the hydrogenation of naphthalene over Ni catalyst: The combined DFT and microkinetic analysis, Fuel, 333, (2023)
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