Preparation of nitrogen and oxygen co-doped porous carbon and study on the performance of Zn-ion hybrid supercapacitors

被引：0
作者：
Cao E.-D. [1 ]
Zhang M.-M. [1 ]
Liu H.-L. [1 ]
Xie R.-L. [1 ]
Tian Y.-J. [1 ]
机构：
[1] School of Chemistry & Chemical Engineering, Anhui Key Laboratory of Coal Clean Conversion and High Valued Utilization, Anhui University of Technology, Ma'anshan
来源：
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology | 2023年 / 51卷 / 04期
关键词：
coal pitch; electrode material; nitrogen-oxygen co-doping; porous carbon; Zn-ion hybrid supercapacitor;
D O I：
10.19906/j.cnki.JFCT.2022070
中图分类号：
学科分类号：
摘要：
In this study, nitrogen-oxygen co-doped porous carbon materials with nano-sheet structure were successfully prepared by template method and chemical activation method using coal pitch with low cost and abundant sources as carbon precursor, urea as nitrogen source and template, and sodium hydroxide as activator. The porous carbon electrodes exhibit a maximum specific capacity of 255.5 mA·h/g at 0.05 A/g and a discharge specific capacity of 78 mA·h/g at 1 A/g. Moreover, the porous carbon electrodes deliver about 72.4% capacitance retention after 12000 cycles and a high energy density of 99.6 W·h/kg, showing great potential as cathode material. The nitrogen-oxygen co-doped porous carbon materials prepared from coal pitch display an excellent electrochemical performance as cathode material for zinc ion hybrid supercapacitors. © 2023 Science Press. All rights reserved.
引用
收藏
页码：544 / 553
页数：9
相关论文
共 40 条
  • [31] LU Y Y, LI Z W, BAI Z Y, MI H Y, JI C C, PANG H, YU C, QIU J S., High energy-power Zn-ion hybrid supercapacitors enabled by layered B/N co-doped carbon cathode[J], Nano Energy, 66, (2019)
  • [32] WANG D W, FANG G L, XUE T, MA J F, GENG G H., A melt route for the synthesis of activated carbon derived from carton box for high performance symmetric supercapacitor applications[J], J Power Sources, 307, (2016)
  • [33] HOU J, CAO C, IDREES F, MA X., Hierarchical porous nitrogen-doped carbon nanosheets derived from silk for ultrahigh-capacity battery anodes and supercapacitors[J], ACS Nano, 9, 3, (2015)
  • [34] LEI Jie, WANG Tao-xiang, LI Zhi, CHEN Hui, YANG Song, HAN Hai-bo, LI Kang, Synthesis of multi-stage pore carbon material with large spacing of carbon layers from asphalt for supercapacitors[J], Chin J Inorg Chem, 37, 7, pp. 1218-1226, (2021)
  • [35] THOMMES M, KANEKO K, NEIMARK A V, OLIVIER J P, RODRIGUEZ-REINOSO F, ROUQUEROL J, SING K S W., Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) [J], Pure Appl Chem, 87, 9, pp. 1051-1069, (2015)
  • [36] CHEN G X, HU Z W, PAN Z M, WANG D W., Design of honeycomb-like hierarchically porous carbons with engineered mesoporosity for aqueous zinc-ion hybrid supercapacitors applications[J], J Energy Storage, 38, (2021)
  • [37] LI H X, WU J, WANG L T, LIAO Q X, NIU X H, ZHANG D Y, WANG K J., A zinc ion hybrid capacitor based on sharpened pencil–like hierarchically porous carbon derived from metal–organic framework[J], Chem Eng J, 428, (2022)
  • [38] LIU P G, LIU W F, HUANG Y P, LI P L, YAN J, LIU K Y., Mesoporous hollow carbon spheres boosted, integrated high performance aqueous Zn–Ion energy storage[J], Energy Storage Mater, 25, pp. 858-865, (2020)
  • [39] YUAN M, CAO B, MENG C Y, ZUO H M, LI A, MA Z K, CHEN X H, SONG H H., Preparation of pitch –based carbon microbeads by a simultaneous spheroidization and stabilization process for lithium-ion batteries[J], Chem Eng J, 400, (2020)
  • [40] SHI M L, CHEN Z Y, SUN J., Determination of chloride diffusivity in concrete by AC impedance spectroscopy[J], Cem Concr Res, 29, 7, (1999)
1234