Enhancing the resilience of cement mortar: Investigating Nano-SiO2 size and hybrid fiber effects on sulfuric acid resistance

This article explores fortifying cement mortars against severe sulfuric acid (SLA) attacks by studying the impact of nano-SiO2 (NS), macro-steel (ST), and micro-polypropylene (PP) fibers. The aim is to assess their effects on workability, physical attributes, mechanical properties, and durability against SLA attacks when incorporated into mortar blends. Replacing 1 % of cement weight with NS, having average particle diameters of 15 nm (nm) (NS15) and 55 nm (NS55), and utilizing macro-ST and micro-PP fibers at volumes of 0.5 % and 1 % in singular and hybrid forms resulted in significant changes in mortar characteristics. While these additives increased fresh mortar viscosity and negatively affected workability, they substantially boosted mortar strength and durability against SLA attacks. The most substantial improvements were observed using smaller NS particle sizes and employing hybrid ST/PP fibers. The formation of calcium-silicatehydrate (C-S-H) bonds by NS within the network emerged as a pivotal factor. NS's high pozzolanic activity and void-filling capacity significantly enhanced the mortars' strength and durability against SLA attacks. Furthermore, instead of their singular application, the combined use of ST and PP fibers proved more effective in restraining micro and macro cracks within the mortar matrix. The bridging effect of hybrid ST/PP fibers delayed crack propagation throughout the network, highlighting their superior efficiency against SLA attacks. Overall, these findings hold promise for designing cement-based composites resilient to harsh, acidic environments. Using smaller NS particles and hybrid fiber combinations presents potential pathways to prolong service life in challenging conditions.