Effect of trace silver on the conductivity and softening temperature of high conductivity and high heat resistance pure copper

被引:0
|
作者
Li, Weiqiang [1 ,2 ]
Liu, Haitao [1 ,2 ,3 ]
Hou, Zhenguo [1 ]
Zhang, Zihao [1 ]
Dong, Jincan [1 ]
Wang, Mengna [4 ]
Guo, Huiwen [4 ]
Song, Kexing [1 ,2 ,3 ]
机构
[1] Henan Univ Sci & Technol, Sch Mat Sci & Engn, Luoyang 471023, Peoples R China
[2] Henan Acad Sci, Inst Mat, Zhengzhou 450046, Peoples R China
[3] Henan Key Lab Adv Cond Mat, Zhengzhou 450046, Peoples R China
[4] Chinalco Luoyang Copper Proc Co Ltd, Luoyang 471039, Peoples R China
来源
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T | 2024年 / 33卷
基金
中国国家自然科学基金;
关键词
Microalloying; Pure copper; Softening resistance; Recrystallization; silver; Solute segregation; HIGH-PURITY COPPER; ELECTRICAL-CONDUCTIVITY; STORED ENERGY; RECRYSTALLIZATION TEXTURES; MECHANICAL-PROPERTIES; THERMAL-STABILITY; HIGH-STRENGTH; CU; MICROSTRUCTURE; COMPOSITE;
D O I
10.1016/j.jmrt.2024.10.156
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
As a conductor material for high-power electronic devices, pure copper requires both conductivity and softening temperature. The effects of 0% (7N Cu), 0.015% (Ag150), 0.030% (Ag300), 0.045% (Ag450) and 0.059% (Ag590) Ag on the microstructure, conductivity and softening temperature of pure copper were studied. The results show that trace Ag can refine the microstructure of pure copper and improve the mechanical properties at room temperature and high temperature. The hardness values of 7N Cu, Ag150, Ag300, Ag450 and Ag590 were 112, 119.06, 122.14, 123.54 and 125.68HV, respectively, and the softening temperatures were 195, 310, 335, 344 and 345 degrees C, respectively. At the same time, the conductivity of the samples with different Ag content was more than 100.5 %IACS. The similar structure of Ag and Cu has little effect on the conductivity. On the one hand, the trace Ag element soluble in the matrix causes lattice distortion, inhibits recrystallization nucleation and grain boundary migration. On the other hand, the Ag element is polarized at the grain boundary, which reduces the grain boundary energy, decreases the atomic diffusion and increases the recrystallization temperature.
引用
收藏
页码:4749 / 4762
页数:14
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