Conductivity Study on Proton-Conducting Nanocomposite Plasticized Polymer Electrolytes: A Review

被引：0
作者：
Sharma S. [1 ]
Pathak D. [2 ,3 ]
Dhiman N. [4 ]
Kumar R. [1 ]
Prashar K.K. [5 ]
Kahol M. [6 ]
Arora N. [7 ]
Sharma V. [1 ,8 ]
机构：
[1] Department of Physics, G.G.D.S.D. College
[2] School of Physics and Materials Science, Shoolini University of Biotechnology & Management Sciences, Solan
[3] Department of Physics, University of West Indies, St Augustine Campus
[4] Department of Physics, TJCM Government College, Sujanpur Tihra
[5] Department of Chemistry, Government Degree College, Sarkaghat
[6] Department of Physics, Government College, Daulatpur, Chowk
[7] P.G. Department of Physics, D.A.V. College, Amritsar
[8] Department of Physics, Panjab University, Chandigarh
来源：
Current Materials Science | 2022年 / 15卷 / 03期
关键词：
composite materials; Ionic conductivity; nanoparticles; spectroscopy; supercapacitors; thermal properties;
D O I：
10.2174/2666145415666220330104918
中图分类号：
学科分类号：
摘要：
This paper reviews proton-conducting polymer electrolytes comprising different pol-ymers, salts, and acids. The ionic conductivity of plasticized polymer electrolytes has been found to increase with the addition of plasticizers due to the dissociation of ion aggregates or undissoci-ated salt/acid present in the electrolytes, i.e., σ (plasticized polymer electrolytes) > σ (unplasti-cized polymer electrolytes). Proton-conducting nonaqueous nanocomposite plasticized polymer electrolytes containing poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP), polymethylmethacrylate (PMMA), polyethylene oxide (PEO) polymers; different ammonium salts and acids as proton conductors; ethylene carbonate (EC), propylene carbonate (PC), dime-thylformamide (DMF), dimethylacetamide (DMA), dimethyl carbonate (DMC), diethyl carbonate (DEC) as plasticizers; fumed silica and alumina as nano-fillers have been discussed in de-tails. Conductivity studies (effect of salt/acid, effect of plasticizers, effect of nano-fillers, and effect of temperature), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and differential scanning calorimetry/thermal gravimetric analysis (DSC/TGA) studies for these electrolytes have been discussed and reported in the paper. Nanocomposite plasticized polymer electrolytes showed high ionic conductivity (in the order of 10-1 to 10-2 S/cm) at room temperature along with good thermal and mechanical stability due to the simultaneous addition of both plasticizers and nano-fillers. These nanocomposite polymer electrolytes are the best candidates for use in various electrochemical devices like solid-state batteries, fuel cells, supercapacitors, sensors, separators, and other electrochromic devices. © 2022 Bentham Science Publishers.
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页码：229 / 250
页数：21
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