Optimizing mechanical and environmental degradation performance of polybutylene adipate terephthalate by adjusting polyvinyl alcohol content

被引:0
作者
Meng, Xuefen [1 ]
Qiu, Jianhui [1 ]
Zhang, Bin [1 ]
Sakai, Eiichi [1 ]
Zhang, Liang [1 ]
Feng, Huixia [2 ]
Tang, Jianhua [1 ]
机构
[1] Akita Prefectural Univ, Fac Syst Sci & Technol, Dept Mech Engn, Akita 0150055, Japan
[2] Lanzhou Univ Technol, Coll Petrochem Technol, Lanzhou 730050, Peoples R China
来源
MATERIALS TODAY COMMUNICATIONS | 2024年 / 41卷
基金
日本学术振兴会;
关键词
PBAT; PVA; Controlled degradation; Mechanical properties; Biodegradation; BIODEGRADATION; BLENDS; SOIL;
D O I
10.1016/j.mtcomm.2024.110786
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Biodegradable plastics offer a promising alternative to traditional plastics in agriculture, particularly where rapid and controlled degradation is required. This study investigates the properties and degradation behavior of blends of Polybutylene Adipate Terephthalate (PBAT) and Polyvinyl Alcohol (PVA). Mechanical testing revealed that incorporating PVA significantly enhanced both tensile and flexural strengths. For example, pure PBAT had a tensile strength of 14.51 MPa, while the 20PBAT/80PVA blend achieved 53.48 MPa. However, higher PVA content led to reduced elongation at break and fracture toughness. Water immersion tests showed that PVA dissolution and PBAT degradation caused notable reductions in mechanical properties after 5 days, with blends containing 80 % PVA exhibiting an 80.1 % weight loss, and the 40PBAT/60PVA blends showing a 41.75 % weight loss after 30 days. Soil degradation experiments confirmed that the degradation rate increased with higher PVA content. These results highlight the superior degradation performance of PBAT/PVA blends and demonstrate that adjusting the PVA content effectively modulates both degradation rates and mechanical properties. This offers valuable insights for the development of environmentally friendly materials.
引用
收藏
页数:10
相关论文
共 47 条
  • [21] An overview on synthesis, properties and applications of poly(butylene-adipate-co-terephthalate)–PBAT
    Jian J.
    Xiangbin Z.
    Xianbo H.
    [J]. Xianbo, Huang (huangxianbo@kingfa.com.cn), 1600, KeAi Communications Co. (03): : 19 - 26
  • [22] Enzymatic degradation of poly (butylene adipate co-terephthalate) (PBAT) copolymer using lipase B from Candida antarctica (CALB) and effect of PBAT on plant growth
    Kanwal, Aqsa
    Zhang, Min
    Sharaf, Faisal
    Li, Chengtao
    [J]. POLYMER BULLETIN, 2022, 79 (10) : 9059 - 9073
  • [23] Mimicking real-field degradation of biodegradable plastics in soil and marine environments: From product utility to end-of-life analysis
    Lee, Junhyeok
    Kim, Semin
    Park, Sung Bae
    Shin, Mira
    Kim, Soyoun
    Kim, Min -Sun
    Shin, Giyoung
    Kang, Taewook
    Kim, Hyo Jeong
    Oh, Dongyeop X.
    Park, Jeyoung
    [J]. POLYMER TESTING, 2024, 131
  • [24] Modulating poly(lactic acid) degradation rate for environmentally sustainable applications
    Liparoti, Sara
    Iozzino, Valentina
    Speranza, Vito
    Pantani, Roberto
    [J]. WASTE MANAGEMENT, 2024, 175 : 215 - 224
  • [25] Enhanced mechanical and biodegradable properties of PBAT/lignin composites via silane grafting and reactive extrusion
    Liu, Yufei
    Liu, Shan
    Liu, Zhentao
    Lei, Yang
    Jiang, Siyuan
    Zhang, Kai
    Yan, Wei
    Qin, Jun
    He, Min
    Qin, Shuhao
    Yu, Jie
    [J]. COMPOSITES PART B-ENGINEERING, 2021, 220
  • [26] Rapid seawater-degradable PBSG/PVA blends: Easy water solubility and easy hydrolysis dual-promoting degradation
    Lu, Bo
    Zhen, Zhi-Chao
    Liu, Tian-Yuan
    Xu, Peng-Yuan
    Wang, Ge-Xia
    Huang, Dan
    Ji, Jun-Hui
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2023, 140 (07)
  • [27] New modifications of PBAT by a small amount of oxalic acid: Fast crystallization and enhanced degradation in all natural environments
    Luan, Qingyang
    Hu, Han
    Ouyang, Xingyu
    Jiang, Xiaoyu
    Lin, Chen
    Zhu, Hanxu
    Shi, Ting
    Zhao, Yi-Lei
    Wang, Jinggang
    Zhu, Jin
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2024, 465
  • [28] Bioinspired fabrication of transparent poly(vinyl alcohol)-based films with excellent strength, ultraviolet blocking performance, and water vapor barrier properties
    Lyu, Yan
    Wu, Ting
    Huang, Cheng
    Ma, Wencan
    Li, Jiongjiong
    Song, Junlong
    Jiao, Jian
    Fang, Guigan
    [J]. INDUSTRIAL CROPS AND PRODUCTS, 2024, 213
  • [29] Biodegradable polymers and composites: Recent development and challenges
    Maurya, Atul Kumar
    de Souza, Felipe Martins
    Dawsey, Tim
    Gupta, Ram K.
    [J]. POLYMER COMPOSITES, 2024, 45 (04) : 2896 - 2918
  • [30] Biodegradable PLA/PBS multinanolayer membrane with enhanced barrier performances
    Messin, Tiphaine
    Marais, Stephane
    Follain, Nadege
    Guinault, Alain
    Gaucher, Valerie
    Delpouve, Nicolas
    Sollogoub, Cyrille
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2020, 598 (598)